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Том 50, № 3 (2016)

Article

Experimental estimation of the vibration effect on the rate of mass transfer from a planar surface

Semenov I., Ul’yanov B., Kulov N.

Аннотация

Mass transfer from a planar surface of a CuSO4 · 5H2O crystal dissolving in water under the action of harmonic vibration in the frequency range from 40 to 100 Kz at amplitudes of 0.1–1 mm has been investigated experimentally. The vibration markedly increases the mass transfer rate. The parameters having the strongest effect on the process have been found and correlated.

Theoretical Foundations of Chemical Engineering. 2016;50(3):231-236
pages 231-236 views

Modeling slug flow and mass transfer in inclined pipes

Pokusaev B., Nekrasov D., Khramtsov D.

Аннотация

An experimental and numerical study of the gas projectile mass transfer when moving in an inclined pipe has been carried out. The mathematical model is based on the smoothed particle hydrodynamics method and verified by experimental data. The dependence of the velocity of the gas projectile motion and effective dimensionless mass transfer coefficient on the pipe inclination angle has been found. The simulated and calculated from experimental data bubble profiles have been compared.

Theoretical Foundations of Chemical Engineering. 2016;50(3):237-241
pages 237-241 views

Model of multicomponent mass transfer in a turbulent bubbling bed based on the concept of an active site

Laptev A., Danilov V., Lapteva E.

Аннотация

The concept of active input portion is considered in vigorous bubbling mode on mass transfer plates of the cross flow. Using active site parameters and the Landau–Levich model of the diffusion boundary layer, equations are obtained and the algorithm is given for calculating the coefficients of mass transfer in liquid and gas phases in multicomponent distillation of mixtures with close thermophysical properties. The results of calculating the mass transfer and mass transport coefficients are compared with the experimental data of various authors. Their satisfactory agreement is established.

Theoretical Foundations of Chemical Engineering. 2016;50(3):242-249
pages 242-249 views

Estimates of energy consumption and selection of optimal distillation sequence for multicomponent distillation

Tsirlin A., Balunov A., Sukin I.

Аннотация

An estimate has been obtained of the energy consumption on 1 mol of separated mixture based on thermodynamic balances for processes that use mechanical and heat energy. Only irreversible losses depend on the order of separation for mixtures in mechanical systems, while for the systems using the heat, the order of separation also affects the reversible energy consumption. In the latter case, in order to obtain a reversible estimate of the heat consumption, one should solve the problem of selecting the order of separation. An algorithm has been obtained for its solution that enables one to approximately choose the order of separation at the stage of preliminary calculations knowing only the properties of the feed.

Theoretical Foundations of Chemical Engineering. 2016;50(3):250-259
pages 250-259 views

Morphological memory of polymers and their use in developing new materials technology

Melikhov I., Rudin V., Alekseeva O., Kozlovskaya E., Adzhiev S.

Аннотация

The problem of the formation of a microrelief on the surfaces of polymeric bodies has been considered. The basis for a mesokinetic model of the formation of macromolecules, their aggregates, and polymeric bodies in a device filled with a monomeric solution has been reported. An equation for changes in the function of the distribution of structural elements of the body microrelief over states in the process of its formation is formulated. Experimental data have been reported on the microrelief of polymeric bodies that confirm the prevalence of morphological memory phenomena among polymers and can be used to create new materials.

Theoretical Foundations of Chemical Engineering. 2016;50(3):260-269
pages 260-269 views

Automodel problem of the growth of the hydrate particle in aqueous solution of gas

Shagapov V., Yumagulova Y.

Аннотация

The problem of the growth of hydrate particle in an aqueous solution of gas, the intensity of which is determined by the diffusion of gas to its surface, is considered. An analytical solution that enables one to determine the law of growth depending on the concentration of the hydrate-forming gas in water and hydrate, as well as the diffusion coefficient, has been obtained.

Theoretical Foundations of Chemical Engineering. 2016;50(3):270-272
pages 270-272 views

Numerical modeling of heat and mass transfer processes upon the flowing of regular structures by gas-droplet stream

Balabekov B., Brener A., Balabekov O.

Аннотация

Approximate models are developed for calculating heat and mass transfer processes in gas-drop flows that pass over a regular packed bed with cylindrical elements. A number of different flow regimes are considered: flat laminar flow, the formation of the stationary vortex behind packing element and formation of nonstationary vortex wake. Criterial equations for calculating corresponding mass transfer parameters are obtained.

Theoretical Foundations of Chemical Engineering. 2016;50(3):273-285
pages 273-285 views

A new class of exact solutions for three-dimensional thermal diffusion equations

Aristov S., Prosviryakov E.

Аннотация

A new class of exact solutions has been obtained for three-dimensional equations of themal diffusion in a viscous incompressible liquid. This class enables the description of the temperature and concentration distribution at the boundaries of a liquid layer by a quadratic law. It has been shown that the solutions of the linearized set of thermal diffusion equations can describe the motion of a liquid at extreme points of hydrodynamic fields. A generalization of the classic Couette flow with a quadratic temperature and concentration distribution at the lower boundary has been considered as an example. The application of the presented class of solutions enables the modeling of liquid counterflows and the construction of exact solutions describing the flows of dissipative media.

Theoretical Foundations of Chemical Engineering. 2016;50(3):286-293
pages 286-293 views

Structural characteristics and state of water in an acetate cellulose membrane

Lazarev S., Golovin Y., Kovalev S.

Аннотация

Experimental data have been obtained and an analysis has been performed of the degree of crystallinity and amorphism and the state of water for cellulose acetate membranes using the methods of X-ray diffraction (XRD), infrared spectroscopy and thermogravimetry. The degree of crystallinity, as well as the crystallite size, have been determined in the membrane samples before and after water absorption. It has been found that OH groups of cellulose acetate form a nonequilibrium network of hydrogen bonds between molecules and fragments in the amorphous phase of an air-dry semipermeable membrane. It has been shown that water that acts as a plasticizer causes the ordering of the macromolecular amorphous phase, which leads to a transition into the liquid crystal phase with the formation of additional capillary spaces.

Theoretical Foundations of Chemical Engineering. 2016;50(3):294-302
pages 294-302 views

Dynamics of a suspension in the presence of liquid filtration, disperse phase sedimentation, and precipitate formation processes

Amanbaev T.

Аннотация

The problem of suspension filtration has been considered with allowance for the formation of a precipitate by sedimenting disperse particles in one-dimensional formulation. The behavior of a suspension is described with a set of equations for the one-dimensional inertialess motion of a two-phase mixture, and the motion of a liquid through a porous precipitate layer has been described with a filtration equation based on the Darcy law. The particular (limit) cases of an equidense suspension (when the densities of both solid and liquid phases are equal) and an equilibrium suspension (when the sizes of particles are small enough to neglect their sedimentation) and the asymptotic case when the density of disperse particles is much greater than the density of a liquid phase have been studied. Some formulas for the characteristic times of disperse phase sedimentation and liquid filtration have been derived. The limit regimes of slow filtration and slow sedimentation are analyzed. In the general case, the problem has been solved in implicit form.

Theoretical Foundations of Chemical Engineering. 2016;50(3):303-315
pages 303-315 views

Techniques to manage geometry characteristics of hollow-fiber membranes

Ivanov M., Dibrov G., Loyko A., Varezhkin A., Kagramanov G.

Аннотация

The process of the dry-wet spinning of asymmetric hollow-fiber membranes has been studied. The set of the parameters of spinning process, which allows the preparation of the smooth, round, and symmetric cross section of a fiber and the given inner and outer diameter so that the hollow-fiber membrane would finally appear as a smooth hollow cylinder, has been determined. The procedure was carried out using the fabrication of hollow fibers from poly(2,6-dimethyl-1,4-phenylene oxide) as an example. The samples with the oxygen permeance Λ/δ (O2) = 400 L/(m2 h bar) and the separation factor corresponding to the properties of material, α(O2/N2) = 4.5, have been obtained. The effective thickness of the selective layer of this membrane is 100 nm. The maximum diameter ratio that has been attained upon dry-wet spinning is 1.4 for the studied polymer solution–internal coagulant system.

Theoretical Foundations of Chemical Engineering. 2016;50(3):316-324
pages 316-324 views

Features of fluid film falling on the corrugated surface of structured packings with perforations

Gorodilov A., Berengarten M., Pushnov A.

Аннотация

Some results of an experimental study of liquid film flow over the surface of a structured packing with a new design for heat and mass exchangers were presented. The influence of the irrigation density on the overflow of liquid from one side of a packing element to the other side was studied. The overflow of liquid from one side of a packing element to the other side was shown to occur abruptly upon attaining a certain irrigation density. A dimensionless quantity, namely, the overflow number, was proposed for estimating uniformity in the distribution of a liquid film over a structured perforated packing bed.

Theoretical Foundations of Chemical Engineering. 2016;50(3):325-334
pages 325-334 views

Mathematical modelling of light dependent microorganisms cultivation in countercurrent film reactor

Shevtsov A., Lytkina L., Antipov S., Ostrikov A., Shentsova E., Drannikov A., Koptev D.

Аннотация

The kinetic parameters of the pseudo-continuous cultivation of green microalgae in the film photobioreactor with countercurrent flows of gas and liquid phases and equipped with spirals on the internal surface of quartz tubes have ben studied. A mathematical model of mass transfer during microalgae cultivation in a film photobioreactor has been developed. The model includes a kinetic equation that considers the effect of the conditions of the cultivation of microalgae populations and cells interactions. A method has been developed for solving equations of the model that uses the Galerkin combination and the finite-element methods.

Theoretical Foundations of Chemical Engineering. 2016;50(3):335-342
pages 335-342 views

Simulation of the separation of a helium–methane mixture in a flat membrane module

Volchkov E., Dvornikov N., Naumkin V.

Аннотация

The problem of the membrane separation of a helium–methane mixture containing 0.1 wt % He, which imitates the composition of a helium-rich natural gas field, has been numerically analyzed. The helium and methane flux distribution along the length of a flat-sheet membrane module have been calculated. The distribution of the average mass concentration of helium in the channels is presented. The gas pumping expenditures have been estimated. The optimal working parameters of the gas mixture have been determined. Heating the mixture above 400 K does not enhance the helium–methane separation efficiency.

Theoretical Foundations of Chemical Engineering. 2016;50(3):343-349
pages 343-349 views