Chemistry of Nepheline Formation in the Batch Mixture in Ceramic Production


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Abstract

Under the conditions of preliminary treatment during the preparation to annealing of a mixture of Tuva clays with the dearsenation cake of the Khovu-Aksy dump sludge, the material was found to undergo a chemical process that forms nepheline. Based on the calculated Gibbs energies of the reactions, it was concluded that the reaction occurs at the minimum number of components in the system: silicate Na4Mg2Si3O10–kaolinite (kaolinite + orthoclase).

About the authors

N. I. Kopylov

Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences

Author for correspondence.
Email: kolyubov@narod.ru
Russian Federation, Novosibirsk, 630090

Yu. D. Kaminskii

Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences

Author for correspondence.
Email: kami@solid.nsc.ru
Russian Federation, Novosibirsk, 630090

B. K. Kasenov

Abishev Institute of Chemical Metallurgy

Email: kami@solid.nsc.ru
Kazakhstan, Karaganda, 100009

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