Electroreduction of chromium(III) chloride in a thermal battery


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The discharge characteristics and the reduction products of the CrCl3 cathodic material in a thermal battery are studied. The maximum discharge capacity of the cathodic material is found to be 0.45 A h g–1 (550°C). A mechanism for the reduction of CrCl3 to metallic chromium via an intermediate formation of the melt of Li3CrCl6x(Br6(1–x)) complexes is proposed.

作者简介

O. Volkova

Institute of High-Temperature Electrochemistry, Ural Branch

编辑信件的主要联系方式.
Email: olga@ihte.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi 22/ul. Akademicheskaya 20, Yekaterinburg, 620137

V. Zakharov

Institute of High-Temperature Electrochemistry, Ural Branch

Email: olga@ihte.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi 22/ul. Akademicheskaya 20, Yekaterinburg, 620137

O. Reznitskikh

Institute of High-Temperature Electrochemistry, Ural Branch

Email: olga@ihte.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi 22/ul. Akademicheskaya 20, Yekaterinburg, 620137


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