Electroreduction of chromium(III) chloride in a thermal battery
- 作者: Volkova O.1, Zakharov V.1, Reznitskikh O.1
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隶属关系:
- Institute of High-Temperature Electrochemistry, Ural Branch
- 期: 卷 2017, 编号 8 (2017)
- 页面: 655-659
- 栏目: Article
- URL: https://journals.rcsi.science/0036-0295/article/view/171646
- DOI: https://doi.org/10.1134/S0036029517080134
- ID: 171646
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详细
The discharge characteristics and the reduction products of the CrCl3 cathodic material in a thermal battery are studied. The maximum discharge capacity of the cathodic material is found to be 0.45 A h g–1 (550°C). A mechanism for the reduction of CrCl3 to metallic chromium via an intermediate formation of the melt of Li3CrCl6x(Br6(1–x)) complexes is proposed.
作者简介
O. Volkova
Institute of High-Temperature Electrochemistry, Ural Branch
编辑信件的主要联系方式.
Email: olga@ihte.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi 22/ul. Akademicheskaya 20, Yekaterinburg, 620137
V. Zakharov
Institute of High-Temperature Electrochemistry, Ural Branch
Email: olga@ihte.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi 22/ul. Akademicheskaya 20, Yekaterinburg, 620137
O. Reznitskikh
Institute of High-Temperature Electrochemistry, Ural Branch
Email: olga@ihte.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi 22/ul. Akademicheskaya 20, Yekaterinburg, 620137