Electrical Conductivities of Solid and Liquid Cryolite Systems
- Авторы: Rudenko A.1, Kataev A.1, Tkacheva O.1,2, Red’kin A.1, Zaikov Y.1,2
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Учреждения:
- Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
- Ural Federal University
- Выпуск: Том 2019, № 2 (2019)
- Страницы: 104-107
- Раздел: Article
- URL: https://journals.rcsi.science/0036-0295/article/view/172913
- DOI: https://doi.org/10.1134/S0036029519020216
- ID: 172913
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Аннотация
The electrical conductivities of the NaF–AlF3 cryolite systems with a cryolite ratio 2.4–3.0 containing 3.0–7.0 wt % CaF2, 1.2–2.0 wt % MgF2 and 0–8.0 wt % Al2O3 in the temperature range 700–1050°C are studied by impedance spectroscopy. The addition of CaF2 or MgF2 to molten sodium cryolite decreases the electrical conductivity. However, below the liquidus temperature in the two-phase solid–liquid region the electrical conductivity increases with the fluoride salt concentration. The electrical conductivities of the cryolite systems decrease with increasing Al2O3 concentration over the entire temperature range.
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Об авторах
A. Rudenko
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: a.rudenko@ihte.uran.ru
Россия, Yekaterinburg, 620137
A. Kataev
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
Email: a.rudenko@ihte.uran.ru
Россия, Yekaterinburg, 620137
O. Tkacheva
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University
Email: a.rudenko@ihte.uran.ru
Россия, Yekaterinburg, 620137; Yekaterinburg, 620002
A. Red’kin
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
Email: a.rudenko@ihte.uran.ru
Россия, Yekaterinburg, 620137
Yu. Zaikov
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences; Ural Federal University
Email: a.rudenko@ihte.uran.ru
Россия, Yekaterinburg, 620137; Yekaterinburg, 620002