Analysis of the geometrical–probabilistic models of electrocrystallization
- Authors: Isaev V.A.1, Grishenkova O.V.1, Zaykov Y.P.1
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Affiliations:
- Institute of High-Temperature Electrochemistry, Ural Branch
- Issue: Vol 2016, No 8 (2016)
- Pages: 776-784
- Section: Article
- URL: https://journals.rcsi.science/0036-0295/article/view/170812
- DOI: https://doi.org/10.1134/S0036029516080061
- ID: 170812
Cite item
Abstract
The formation of a three-dimensional electrode deposit under potentiostatic conditions, including the stages of nucleation, growth, and overlap of growing new-phase clusters and their diffusion zones, is considered. The models of electrochemical phase formation for kinetics- and diffusion-controlled growth are analyzed, and the correctness of the approximations used in these models is estimated. The possibility of application of these models to an analysis of the electrodeposition of silicon from molten salts is discussed.
Keywords
About the authors
V. A. Isaev
Institute of High-Temperature Electrochemistry, Ural Branch
Author for correspondence.
Email: v.isaev@ihte.uran.ru
Russian Federation, ul. S. Kovalevskoi 22/ul. Akademicheskaya 20, Yekaterinburg, 620137
O. V. Grishenkova
Institute of High-Temperature Electrochemistry, Ural Branch
Email: v.isaev@ihte.uran.ru
Russian Federation, ul. S. Kovalevskoi 22/ul. Akademicheskaya 20, Yekaterinburg, 620137
Yu. P. Zaykov
Institute of High-Temperature Electrochemistry, Ural Branch
Email: v.isaev@ihte.uran.ru
Russian Federation, ul. S. Kovalevskoi 22/ul. Akademicheskaya 20, Yekaterinburg, 620137