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Vol 2017, No 6 (2017)

Simulation of Metallurgical and Thermal Processes

Hydraulic simulation of the replacement of submerged nozzles in slab continuous casters

Eron’ko S.P., Tkachev M.Y., Oshovskaya E.V.

Abstract

A physical model is used to study the effect of submerged nozzles during their replacement on the trajectory of motion of the metal streams in the mold of a slag continuous caster in the course of casting. Recommendations are made to decrease the time of action of this factor on the ingot formation conditions.

Russian Metallurgy (Metally). 2017;2017(6):441-446
pages 441-446 views

Simulation of the sulfide phase formation in a KhN60VT alloy

Kabanov I.V., Butskii E.V., Grigorovich K.V., Arsenkin A.M.

Abstract

The conditions of the existence of sulfide phases in Fe–Ni–S alloys and four-component Fe–50 wt % Ni–0.001 wt % S–R (R is an alloying or impurity element from the TCFE7 database) systems are studied using the Thermo-Calc software package and the TCFE7 database. The modification of nickel superalloys by calcium or magnesium is shown to increase their ductility due to partial desulfurization, the suppression of the formation of harmful sulfide phases, and the uniform formation of strong sulfides in the entire temperature range of metal solidification. The manufacturability of superalloys can decrease at a too high calcium or magnesium content because of the formation of intermetallics with a low melting temperature along grain boundaries.

Russian Metallurgy (Metally). 2017;2017(6):447-453
pages 447-453 views

Manufacture of Ferrous and Nonferrous Metals

Adjusting characteristics of electric arc furnaces

Mironov Y.M., Mironova A.N., Mikhadarov D.G.

Abstract

The dependences of the electric and electrotechnological parameters of electric arc furnaces on the arc length in different heat periods are considered.

Russian Metallurgy (Metally). 2017;2017(6):454-460
pages 454-460 views

In situ formation of the composite structure of a eutectic Nb–Si alloy during directional solidification in a liquid-metal coolant

Bondarenko Y.A., Echin A.B., Kolodyazhnyi M.Y.

Abstract

The results of investigation of the structure of a heat-resistant eutectic niobium–silicon alloy, which was prepared by directional solidification using a liquid-metal coolant, are reported. The typical areas of the macrostructure of an ingot undergone directional solidification are considered, and the composition and the volume fractions of the Nb–Si composite have been determined.

Russian Metallurgy (Metally). 2017;2017(6):461-466
pages 461-466 views

Theory of Metallurgical Processes

Metallurgical features of the formation of a solid-phase metal joint upon electric-circuit heating

Latypov R.A., Bulychev V.V., Zybin I.N.

Abstract

The thermodynamic conditions of formation of a joint between metals using the solid-phase methods of powder metallurgy, welding, and deposition of functional coatings upon electric-current heating of the surfaces to be joined are studied. Relations are obtained to quantitatively estimate the critical sizes of the circular and linear active centers that result in the formation of stable bonding zones.

Russian Metallurgy (Metally). 2017;2017(6):467-471
pages 467-471 views

Mechanism and kinetics of reaction diffusion in steels under the conditions of simultaneous external and internal oxidation

Korostelev A.B.

Abstract

Thermodynamic prerequisites for the formation of internal oxidation zones in multicomponent alloys (metal-solvent + alloying element + insertion element (oxygen, nitrogen, carbon)) are presented. The kinetics of changing the component concentrations upon the formation of one- and two-phase oxide layers is shown. The boundary conditions for the formation of the internal oxidation zones are determined.

Russian Metallurgy (Metally). 2017;2017(6):472-476
pages 472-476 views

Angle of wetting of aluminum oxide with a high-carbon iron melt

Anikeev A.N., Valenza F., Passerone A., Chumanov I.V.

Abstract

The angle of wetting of aluminum oxide with a high-carbon iron melt is studied as a function of temperature and time. It is found that the angle is nearly 94° in the temperature range 1200–1400°C. A preliminary study of the interface is performed using confocal and scanning electron microscopy.

Russian Metallurgy (Metally). 2017;2017(6):477-482
pages 477-482 views

Special Electrometallurgy

Mechanical properties of the welded joints of 1565ch alloy sheets at low temperatures

Ovchinnikov V.V., Drits A.M., Gureeva M.A., Malov D.V., Rastopchin R.N.

Abstract

The effect of the method of welding on the mechanical properties of the welded joints of the 1565chM alloy is studied at room, high, and low temperatures.

Russian Metallurgy (Metally). 2017;2017(6):483-488
pages 483-488 views

Hardening and Coating Technologies

Electrochemical borating of titanium-containing carbographite materials

Gorlanov E.S., Bazhin V.Y., Vlasov A.A.

Abstract

The regularities and mechanism of the electrochemical borating of cathodic carbographite materials under the conditions of electrolysis of cryolite–alumina melts are studied. The effect of carbon surface wetting is proved to take place upon the formation of a melted aluminum layer at a cathode. These facts are confirmed by X-ray diffraction analysis of the surface layer of the cathode. Compounds TiC and TiB2 are observed. The mechanisms of electrochemical and physical processes of the formation of Ti–B–C complexes in the surface layers of the cathode are studied.

Russian Metallurgy (Metally). 2017;2017(6):489-493
pages 489-493 views

Erosion-resistant coatings for gas turbine engine compressor blades

Kablov E.N., Muboyadzhyan S.A.

Abstract

The erosion-resistant ZrN and Cr3C2 coatings intended for the protection of the titanium and steel blades in a GTE compressor are studied. The erosion resistance of the substrate–coating composition is shown to depend on the coating thickness, the deposition conditions, and the coating texture. Ion-assisted deposition changes the structure–phase state of a coating and substantially increases its erosion resistance. It is found that a nanolayer 2D TiN/CrN coating with an average nanolayer thickness of ~60 nm is the best erosion- corrosion-resistant coating for titanium alloys and that a (NiCrTiAlHf)C + CrC coating formed by ionassisted deposition is the best coating for steels. The testing of alloy VT8 compressor blades in an engine supported high protective properties of the nanolayer TiN/CrN coating.

Russian Metallurgy (Metally). 2017;2017(6):494-504
pages 494-504 views

Restoration of the wear-resistant coatings on a GTE compressor airfoil shroud platform

Abraimov N.V., Geikin V.A., Chekalova E.A., Lukina V.V.

Abstract

The deposition of a VT20 alloy onto the airfoil shroud platform of a compressor in an argon atmosphere and the composition, the structure, and the properties of a restored wear-resistant VK-25M coating are studied. The coating deposited onto the built-up material is found to contain (%) 3–4 C, 72–74 W, and 23–24 Co. This coating does not undergo cracking when a diamond pyramid is indented at a load of 50 kg or a diamond cone is indented at a load of 100 kg at a layer thickness of 0.15, 0.25, and 0.38 mm.

Russian Metallurgy (Metally). 2017;2017(6):505-510
pages 505-510 views

Experimental-calculation study of ion-plasma thermal barrier coatings for turbine blades made of intermetallic nickel superalloys

Budinovskii S.A., Matveev P.V., Zhivushkin A.A., Tikhomirova E.A., Belyaeva L.A., Balakin S.M.

Abstract

The ion-plasma thermal barrier coatings deposited onto samples and blades made of intermetallic VKNA-1V and VKNA-25 alloys are tested in a laboratory. The external ceramic layer of the thermal barrier coatings (TBC) is formed by magnetron sputtering of zirconium alloy targets and has a columnar structure. The influence of NiCrAlY(Re, Ta, Hf) + AlNiY(Hf) + ZrYGdO TBC on the long-term strength at a test temperature of 1200°C and on the high-cycle fatigue at a temperature of 900°C is studied. Blades with TBC are subjected to thermal cycling tests in the temperature range 950 ↔ 400°C and 1050 ↔ 400°C during air cooling and in the range 950 ↔ 200°C during water cooling at 500 cycles. The temperature fields in the cross section of a blade airfoil during thermal cycling are calculated. The laws of formation of fracture zones and the development of thermal fatigue cracks under the conditions that are close to the operating conditions of nozzle TBC-containing blades are investigated.

Russian Metallurgy (Metally). 2017;2017(6):511-519
pages 511-519 views

Heterogeneous structure and fracture of iron-based alloys and their measurement

Kudrya A.V., Sokolovskaya E.A., Akhmedova T.S., Perezhogin V.Y.

Abstract

The possibilities of computerized procedures for comparing the heterogeneous structures and the fractures of hard alloys are estimated in order to evaluate the factors determining the wear resistance of hard iron-based alloys and premature fracture.

Russian Metallurgy (Metally). 2017;2017(6):520-526
pages 520-526 views

Control of Technological Processes

Erosion of plasma generator electrodes for various power supplies

Cherednichenko M.V., Serikov V.A., Butakov E.B., Urbakh A.E.

Abstract

The increase in the erosion of plasma generator electrodes with controlled rectifiers that is caused by the appearance of a pulsed current component when the power supply voltage and power decrease is experimentally studied. The recommendation of using plasma generators under nominal operating conditions of power supplies with short periods of low-current operation is substantiated.

Russian Metallurgy (Metally). 2017;2017(6):527-531
pages 527-531 views

Problems of Economics

Influence of market factors on the pricing of exchange traded metals in the medium term

Bogdanov S.V., Shevelev I.M., Chernyi S.A.

Abstract

On the basis of comparison of the influence of the stock exchange factors on the pricing of nonferrous metals for medium term with similar results for short term, it has been established that the main attention should be paid to the changes in the pricing environment on the metal market as a function of the prices of exchange traded metals. The situation on the market of energy carriers (hydrocarbons) and the European, American, and Asian stock exchanges can be based on parity and even significantly influence the variation of the metal prices. In the medium term, constructive development of metal trade should be reasonably promoted by changing the elasticity of supply with regard to prices for exchange traded metals and by applying the stock exchange factors that positively influence the pricing on commodity and stock markets.

Russian Metallurgy (Metally). 2017;2017(6):532-537
pages 532-537 views

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