Email this article Electroreduction of Chromium(III) Chloride and Molybdenum(VI) Oxide Mixtures in a Thermally Activated Battery
- Authors: Volkova O.V.1, Zakharov V.V.1
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Affiliations:
- Institute of High-Temperature Electrochemistry, Ural Branch
- Issue: Vol 2018, No 2 (2018)
- Pages: 201-204
- Section: Article
- URL: https://journals.rcsi.science/0036-0295/article/view/172351
- DOI: https://doi.org/10.1134/S0036029518020234
- ID: 172351
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Abstract
The discharge characteristics of a thermally activated battery element with cathode materials based on CrCl3–MoO3 mixtures are studied. The composition and the morphology of the products of reduction of the cathode materials are determined. A mechanism is proposed for their reduction to metallic chromium and molybdenum through an intermediate stage of formation of the melts of the complex Li3CrCl6 compound and lithium molybdates with lithium chloride.
About the authors
O. V. Volkova
Institute of High-Temperature Electrochemistry, Ural Branch
Author for correspondence.
Email: olga@ihte.uran.ru
Russian Federation, ul. Akademicheskaya 20, Yekaterinburg, 620137
V. V. Zakharov
Institute of High-Temperature Electrochemistry, Ural Branch
Email: olga@ihte.uran.ru
Russian Federation, ul. Akademicheskaya 20, Yekaterinburg, 620137
