Electrical Conductivity and Raman Spectra of Disperse Systems α-Al2O3–Li2CO3–Na2CO3–K2CO3–NaCl Melt


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Abstract

The conductivities of the disperse system α-Al2O3–molten carbonate chloride mixture Li2CO3–Na2CO3–K2CO3–NaCl are dtermined in the temperature range 455–550°C. As follows from Raman spectroscopy data, α-Al2O3 does not interact chemically with the carbonate–chloride melt in this temperature range. The force and energy characteristics of the CO32- anion in the systems are revealed.

About the authors

I. D. Zakir’yanova

Institute of High Temperature Electrochemistry; Ural Federal University

Author for correspondence.
Email: optica96@ihte.uran.ru
Russian Federation, Yekaterinburg, 620000; Yekaterinburg, 620002

E. V. Nikolaeva

Institute of High Temperature Electrochemistry; Ural Federal University; Ural State University of Economics

Email: optica96@ihte.uran.ru
Russian Federation, Yekaterinburg, 620000; Yekaterinburg, 620002; Yekaterinburg, 620144

A. L. Bove

Institute of High Temperature Electrochemistry; Ural Federal University

Email: optica96@ihte.uran.ru
Russian Federation, Yekaterinburg, 620000; Yekaterinburg, 620002

B. D. Antonov

Institute of High Temperature Electrochemistry

Email: optica96@ihte.uran.ru
Russian Federation, Yekaterinburg, 620000


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