Preparation of a Nickel–Holmium Alloy Coating in an Equimolar HoCl3-Containing NaCl–KCl Melt
- Authors: Bushuev A.N.1, El’kin O.V.1, Tolstobrov I.V.1, Sazanov A.V.1, Kondrat’ev D.A.1
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Affiliations:
- Vyatka State University, Institute of Chemistry and Ecology
- Issue: Vol 2018, No 8 (2018)
- Pages: 771-776
- Section: Article
- URL: https://journals.rcsi.science/0036-0295/article/view/172077
- DOI: https://doi.org/10.1134/S0036029518080049
- ID: 172077
Cite item
Abstract
Cyclic voltammetry is used to study the electrolytic reduction of holmium ions on a nickel electrode in a holmium chloride-containing equimolar molten mixture of sodium and potassium chlorides in a temperature range of 1073–1173 K. The potentials of formation of nickel–holmium intermetallic compounds (IMCs) are determined. Nickel–holmium intermetallic compounds are synthesized by controlled potential electrolysis. Under the selected electrolysis conditions, the prepared coating is shown to be single-phase and its composition corresponds to the HoNi2 stoichiometry. The coefficients of reaction diffusion of holmium in nickel are calculated and the activation energy of alloy-formation process is determined.
About the authors
A. N. Bushuev
Vyatka State University, Institute of Chemistry and Ecology
Author for correspondence.
Email: nihilanth@mail.ru
Russian Federation, Kirov, 610000
O. V. El’kin
Vyatka State University, Institute of Chemistry and Ecology
Email: nihilanth@mail.ru
Russian Federation, Kirov, 610000
I. V. Tolstobrov
Vyatka State University, Institute of Chemistry and Ecology
Email: nihilanth@mail.ru
Russian Federation, Kirov, 610000
A. V. Sazanov
Vyatka State University, Institute of Chemistry and Ecology
Email: nihilanth@mail.ru
Russian Federation, Kirov, 610000
D. A. Kondrat’ev
Vyatka State University, Institute of Chemistry and Ecology
Email: nihilanth@mail.ru
Russian Federation, Kirov, 610000