Simulation of the potentiodynamic and galvanostatic phase formation in melts

V. A. Isaev; O. V. Grishenkova; A. V. Kosov; O. L. Semerikova; Yu. P. Zaykov

doi:10.1134/S0036029517020057

Simulation of the potentiodynamic and galvanostatic phase formation in melts

Authors: Isaev V.A.¹, Grishenkova O.V.¹, Kosov A.V.¹, Semerikova O.L.¹, Zaykov Y.P.¹
Affiliations:
1. Institute of High-Temperature Electrochemistry, Ural Branch
Issue: Vol 2017, No 2 (2017)
Pages: 146-151
Section: Article
URL: https://journals.rcsi.science/0036-0295/article/view/171282
DOI: https://doi.org/10.1134/S0036029517020057
ID: 171282

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Abstract

A general scheme is used to consider the initial stages of electrocrystallization under potentiodynamic and galvanostatic conditions. Proposed theoretical models are shown to agree well with the experimental results obtained during the electrodeposition of silver crystals on an iridium microelectrode from nitrate melt containing an excess background electrolyte.