Thermodynamic simulation of the oxidation of radioactive graphite in the Na2CO3–K2CO3–NiO and Na2CO3–K2CO3–CuO melts


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Abstract

The oxidation of radioactive graphite in the Na2CO3–K2CO3–NiO and Na2CO3–K2CO3–CuO melts in the temperature range 373–3273 K is subjected to a thermodynamic simulation. The behavior of radionuclides is studied and the equilibrium constants of the reactions occurring in these systems are calculated.

About the authors

N. M. Barbin

Ural State Agrarian University; Ural State Fire Service Institute of Emercom of Russia; Federal State Autonomous Educational Institution of Higher Education “Ural Federal University named after the first President of Russia B.N. Yeltsin”

Author for correspondence.
Email: NMBarbin@mail.ru
Russian Federation, ul. K. Libknekht 42, Yekaterinburg, 620075; ul. Mira 22, Yekaterinburg, 620062; ul. Mira 19, Yekaterinburg, 620002

M. R. Shavaleev

Ural State Fire Service Institute of Emercom of Russia

Author for correspondence.
Email: marat-shavaleev@mail.ru
Russian Federation, ul. Mira 22, Yekaterinburg, 620062

D. I. Terent’ev

Ural State Fire Service Institute of Emercom of Russia

Email: marat-shavaleev@mail.ru
Russian Federation, ul. Mira 22, Yekaterinburg, 620062

S. G. Alekseev

Ural State Fire Service Institute of Emercom of Russia

Email: marat-shavaleev@mail.ru
Russian Federation, ul. Mira 22, Yekaterinburg, 620062


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