Email this article Stabilization of the fluorite phase in the ZrO2–Y2O3 system
- Authors: Tsarenko N.A.1, Udovskii A.L.2,3, Popov V.V.2, Yastrebtsev A.A.2, Smirnov I.S.4, Monakhov I.S.4, Novoselova E.G.4
-
Affiliations:
- JSC Scientific Research Institute of Chemical Technology
- National Research Nuclear University MEPhI (Moscow Engineering Physics Institute)
- Baikov Institute of Metallurgy and Materials Science
- National Research University Higher School of Economics
- Issue: Vol 2016, No 9 (2016)
- Pages: 869-874
- Section: Article
- URL: https://journals.rcsi.science/0036-0295/article/view/170879
- DOI: https://doi.org/10.1134/S0036029516090111
- ID: 170879
Cite item
Open Access
Access granted
Subscription Access
Abstract
The calculated and experimental vertical ZrO2–Y2O3 sections of the Zr–Y–O system are compared to find the region of a stable fluorite structure of yttrium-stabilized zirconia (YSZ). X-ray diffraction (XRD) and Raman scattering are used to study the crystal and local structures of mixed oxide 0.82ZrO2 · 0.18Y2O3 (18YSZ) powders prepared by isothermal annealing of a precursor precipitated from a salt solution. The formation of a fluorite-type fcc structure (space group \(Fm\overline 3 m\)) in the powders is detected by XRD. Raman scattering study of the local structure of the cubic 18YSZ powders revealed traces of the tetragonal phase in them.
About the authors
N. A. Tsarenko
JSC Scientific Research Institute of Chemical Technology
Email: victorvpopov@mail.ru
Russian Federation, Kashirskoye sh. 33, Moscow, 115409
A. L. Udovskii
National Research Nuclear University MEPhI (Moscow Engineering Physics Institute); Baikov Institute of Metallurgy and Materials Science
Email: victorvpopov@mail.ru
Russian Federation, Kashirskoye sh. 31, Moscow, 115409; Leninskii pr. 49, Moscow, 119991
V. V. Popov
National Research Nuclear University MEPhI (Moscow Engineering Physics Institute)
Author for correspondence.
Email: victorvpopov@mail.ru
Russian Federation, Kashirskoye sh. 31, Moscow, 115409
A. A. Yastrebtsev
National Research Nuclear University MEPhI (Moscow Engineering Physics Institute)
Email: victorvpopov@mail.ru
Russian Federation, Kashirskoye sh. 31, Moscow, 115409
I. S. Smirnov
National Research University Higher School of Economics
Email: victorvpopov@mail.ru
Russian Federation, ul. Myasnitskaya 20, Moscow, 101000
I. S. Monakhov
National Research University Higher School of Economics
Email: victorvpopov@mail.ru
Russian Federation, ul. Myasnitskaya 20, Moscow, 101000
E. G. Novoselova
National Research University Higher School of Economics
Email: victorvpopov@mail.ru
Russian Federation, ul. Myasnitskaya 20, Moscow, 101000
