Methods for calculating the kinetic parameters of carbonate decomposition from thermal analysis data

I. V. Artamonova; I. G. Gorichev; Yu. A. Lainer; E. B. Godunov; S. M. Kramer; M. V. Terekhova

doi:10.1134/S0036029516070041

Methods for calculating the kinetic parameters of carbonate decomposition from thermal analysis data

Authors: Artamonova I.V.¹, Gorichev I.G.¹, Lainer Y.A.², Godunov E.B.¹, Kramer S.M.¹, Terekhova M.V.¹
Affiliations:
1. Moscow Polytechnical University
2. Baikov Institute of Metallurgy and Materials Science
Issue: Vol 2016, No 7 (2016)
Pages: 592-595
Section: Article
URL: https://journals.rcsi.science/0036-0295/article/view/170640
DOI: https://doi.org/10.1134/S0036029516070041
ID: 170640

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Abstract

A procedure is proposed for an analysis of the data on the decomposition of inorganic carbonates (MgCO₃, CaCO₃, SrCO₃, MnCO₃, CoCO₃) on the basis of results of thermogravimetric studies. The activation energy and the rate constant for carbonate decomposition are calculated taking into account the main points of the heterogeneous reaction kinetics. A comparative analysis of the obtained results is performed.