Algorithm for Calculating the Dissociation Constants of Ampholytes in Nonbuffer Systems
- 作者: Lysova S.1, Skripnikova T.1, Zevatskii Y.1,2,3
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隶属关系:
- St. Petersburg State University of Industrial Technologies and Design
- ZAO Novbytkhim
- St. Petersburg State Electrotechnical University (LETI)
- 期: 卷 92, 编号 5 (2018)
- 页面: 922-926
- 栏目: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0244/article/view/169999
- DOI: https://doi.org/10.1134/S0036024418050229
- ID: 169999
如何引用文章
详细
An algorithm for calculating the dissociation constants of ampholytes in aqueous solutions is developed on the basis of spectrophotometric data in the UV and visible ranges without pH measurements of a medium and without buffer solutions. The proposed algorithm has been experimentally tested for five ampholytes of different strengths. The relative error of measuring dissociation constants is less than 5%.
作者简介
S. Lysova
St. Petersburg State University of Industrial Technologies and Design
编辑信件的主要联系方式.
Email: lusovass@mail.ru
俄罗斯联邦, St. Petersburg, 191186
T. Skripnikova
St. Petersburg State University of Industrial Technologies and Design
Email: lusovass@mail.ru
俄罗斯联邦, St. Petersburg, 191186
Yu. Zevatskii
St. Petersburg State University of Industrial Technologies and Design; ZAO Novbytkhim; St. Petersburg State Electrotechnical University (LETI)
Email: lusovass@mail.ru
俄罗斯联邦, St. Petersburg, 191186; Gatchina, 199026; St. Petersburg, 197022