Algorithm for Calculating the Dissociation Constants of Ampholytes in Nonbuffer Systems


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详细

An algorithm for calculating the dissociation constants of ampholytes in aqueous solutions is developed on the basis of spectrophotometric data in the UV and visible ranges without pH measurements of a medium and without buffer solutions. The proposed algorithm has been experimentally tested for five ampholytes of different strengths. The relative error of measuring dissociation constants is less than 5%.

作者简介

S. Lysova

St. Petersburg State University of Industrial Technologies and Design

编辑信件的主要联系方式.
Email: lusovass@mail.ru
俄罗斯联邦, St. Petersburg, 191186

T. Skripnikova

St. Petersburg State University of Industrial Technologies and Design

Email: lusovass@mail.ru
俄罗斯联邦, St. Petersburg, 191186

Yu. Zevatskii

St. Petersburg State University of Industrial Technologies and Design; ZAO Novbytkhim; St. Petersburg State Electrotechnical University (LETI)

Email: lusovass@mail.ru
俄罗斯联邦, St. Petersburg, 191186; Gatchina, 199026; St. Petersburg, 197022


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