Materials based on cellulose fabric and PVC with porous structures formed by jointed aza- and oxa-aza-crown macromolecules


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详细

A material with porous structures formed by jointed aza- and oxa-aza-crowns with peripheral OHgroups is synthesized on the basis of cellulose fabric and PVC transformed into hydroxyethylcyclam. Mesopores are mainly observed on the fiber surface. The specific surface of the material is 6 m2/g; the volume of free space is 0.112 cm3/g. Assuming the internal pores have a disk-like shape, their width is estimated at 2 nm. The material sorbs vapors of aliphatic and aromatic hydrocarbons, alcohols, aldehydes, ketones, amines, amides, nitriles, and sulfoxides. It also swells to a limited degree in organic solvents. When sulfuric acid or sodium hydroxide is sorbed in the pores, compounds of them with H+- and OH-conducting systems of hydrogen bonds are formed.

作者简介

A. Fridman

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

A. Tsivadze

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

E. Morozova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

N. Sokolova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

A. Shiryaev

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

G. Petukhova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

A. Voloshchuk

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

I. Bardyshev

Frumkin Institute of Physical Chemistry and Electrochemistry

编辑信件的主要联系方式.
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

A. Gorbunov

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

I. Polyakova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

A. Novikov

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

V. Titova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

A. Yavich

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071

N. Petrova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071


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