Materials based on cellulose fabric and PVC with porous structures formed by jointed aza- and oxa-aza-crown macromolecules
- 作者: Fridman A.1, Tsivadze A.1, Morozova E.1, Sokolova N.1, Shiryaev A.1, Petukhova G.1, Voloshchuk A.1, Bardyshev I.1, Gorbunov A.1, Polyakova I.1, Novikov A.1, Titova V.1, Yavich A.1, Petrova N.1
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隶属关系:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- 期: 卷 90, 编号 12 (2016)
- 页面: 2453-2458
- 栏目: Physical Chemistry of Surface Phenomena
- URL: https://journals.rcsi.science/0036-0244/article/view/169063
- DOI: https://doi.org/10.1134/S0036024416120104
- ID: 169063
如何引用文章
详细
A material with porous structures formed by jointed aza- and oxa-aza-crowns with peripheral OHgroups is synthesized on the basis of cellulose fabric and PVC transformed into hydroxyethylcyclam. Mesopores are mainly observed on the fiber surface. The specific surface of the material is 6 m2/g; the volume of free space is 0.112 cm3/g. Assuming the internal pores have a disk-like shape, their width is estimated at 2 nm. The material sorbs vapors of aliphatic and aromatic hydrocarbons, alcohols, aldehydes, ketones, amines, amides, nitriles, and sulfoxides. It also swells to a limited degree in organic solvents. When sulfuric acid or sodium hydroxide is sorbed in the pores, compounds of them with H+- and OH–-conducting systems of hydrogen bonds are formed.
作者简介
A. Fridman
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
E. Morozova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
N. Sokolova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
A. Shiryaev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
G. Petukhova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
A. Voloshchuk
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
I. Bardyshev
Frumkin Institute of Physical Chemistry and Electrochemistry
编辑信件的主要联系方式.
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
A. Gorbunov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
I. Polyakova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
A. Novikov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
V. Titova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
A. Yavich
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071
N. Petrova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
俄罗斯联邦, Moscow, 119071