Отправить статью по E-mail Materials based on cellulose fabric and PVC with porous structures formed by jointed aza- and oxa-aza-crown macromolecules
- Авторы: Fridman A.Y.1, Tsivadze A.Y.1, Morozova E.M.1, Sokolova N.P.1, Shiryaev A.A.1, Petukhova G.A.1, Voloshchuk A.M.1, Bardyshev I.I.1, Gorbunov A.M.1, Polyakova I.Y.1, Novikov A.K.1, Titova V.N.1, Yavich A.A.1, Petrova N.V.1
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Учреждения:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Выпуск: Том 90, № 12 (2016)
- Страницы: 2453-2458
- Раздел: Physical Chemistry of Surface Phenomena
- URL: https://journals.rcsi.science/0036-0244/article/view/169063
- DOI: https://doi.org/10.1134/S0036024416120104
- ID: 169063
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Аннотация
A material with porous structures formed by jointed aza- and oxa-aza-crowns with peripheral OHgroups is synthesized on the basis of cellulose fabric and PVC transformed into hydroxyethylcyclam. Mesopores are mainly observed on the fiber surface. The specific surface of the material is 6 m2/g; the volume of free space is 0.112 cm3/g. Assuming the internal pores have a disk-like shape, their width is estimated at 2 nm. The material sorbs vapors of aliphatic and aromatic hydrocarbons, alcohols, aldehydes, ketones, amines, amides, nitriles, and sulfoxides. It also swells to a limited degree in organic solvents. When sulfuric acid or sodium hydroxide is sorbed in the pores, compounds of them with H+- and OH–-conducting systems of hydrogen bonds are formed.
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Об авторах
A. Fridman
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
E. Morozova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
N. Sokolova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Shiryaev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
G. Petukhova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Voloshchuk
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
I. Bardyshev
Frumkin Institute of Physical Chemistry and Electrochemistry
Автор, ответственный за переписку.
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Gorbunov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
I. Polyakova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Novikov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
V. Titova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
A. Yavich
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
N. Petrova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Россия, Moscow, 119071
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