电邮这篇文章 Paramagnetic properties of triple molybdates CsNa5M3(MoO4)6 (M = Ni, Co, Mn)
- 作者: Shkerin S.N.1, Uporov S.A.2, Yudin V.N.3, Solodovnikov S.F.3,4, Zolotova E.S.3, Tolkacheva A.S.1,5
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隶属关系:
- Institute of High-Temperature Electrochemistry, Ural Branch
- Institute of Metallurgy, Ural Branch
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- National Research Novosibirsk State University
- Institute of Materials Science and Metallurgy
- 期: 卷 90, 编号 11 (2016)
- 页面: 2292-2296
- 栏目: Photochemistry and Magnetochemistry
- URL: https://journals.rcsi.science/0036-0244/article/view/168992
- DOI: https://doi.org/10.1134/S0036024416110248
- ID: 168992
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详细
The static magnetization of CsNa5M3(MoO4)6 single phase molybdates, where M = Co, Ni, and Mn, is measured at 4–300 K in magnetic fields of up to 20 kOe. It is shown that the materials are paramagnetic. Magnetization as a function of temperature is described using the Curie–Weiss law. The intrinsic magnetic moments of the phases are found to be 9.759 (Co), 6.958 (Ni), and 12.203 Bohr magnetons for manganese molybdates. It is concluded that the charge state of Co, Ni, and Mn cations in the compounds is +2.
作者简介
S. Shkerin
Institute of High-Temperature Electrochemistry, Ural Branch
编辑信件的主要联系方式.
Email: shkerin@mail.ru
俄罗斯联邦, Yekaterinburg, 620137
S. Uporov
Institute of Metallurgy, Ural Branch
Email: shkerin@mail.ru
俄罗斯联邦, Yekaterinburg, 620016
V. Yudin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: shkerin@mail.ru
俄罗斯联邦, Novosibirsk, 630090
S. Solodovnikov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; National Research Novosibirsk State University
Email: shkerin@mail.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090
E. Zolotova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: shkerin@mail.ru
俄罗斯联邦, Novosibirsk, 630090
A. Tolkacheva
Institute of High-Temperature Electrochemistry, Ural Branch; Institute of Materials Science and Metallurgy
Email: shkerin@mail.ru
俄罗斯联邦, Yekaterinburg, 620137; Yekaterinburg, 620083
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