Отправить статью по E-mail Paramagnetic properties of triple molybdates CsNa5M3(MoO4)6 (M = Ni, Co, Mn)
- Авторы: Shkerin S.N.1, Uporov S.A.2, Yudin V.N.3, Solodovnikov S.F.3,4, Zolotova E.S.3, Tolkacheva A.S.1,5
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Учреждения:
- Institute of High-Temperature Electrochemistry, Ural Branch
- Institute of Metallurgy, Ural Branch
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- National Research Novosibirsk State University
- Institute of Materials Science and Metallurgy
- Выпуск: Том 90, № 11 (2016)
- Страницы: 2292-2296
- Раздел: Photochemistry and Magnetochemistry
- URL: https://journals.rcsi.science/0036-0244/article/view/168992
- DOI: https://doi.org/10.1134/S0036024416110248
- ID: 168992
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Аннотация
The static magnetization of CsNa5M3(MoO4)6 single phase molybdates, where M = Co, Ni, and Mn, is measured at 4–300 K in magnetic fields of up to 20 kOe. It is shown that the materials are paramagnetic. Magnetization as a function of temperature is described using the Curie–Weiss law. The intrinsic magnetic moments of the phases are found to be 9.759 (Co), 6.958 (Ni), and 12.203 Bohr magnetons for manganese molybdates. It is concluded that the charge state of Co, Ni, and Mn cations in the compounds is +2.
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S. Shkerin
Institute of High-Temperature Electrochemistry, Ural Branch
Автор, ответственный за переписку.
Email: shkerin@mail.ru
Россия, Yekaterinburg, 620137
S. Uporov
Institute of Metallurgy, Ural Branch
Email: shkerin@mail.ru
Россия, Yekaterinburg, 620016
V. Yudin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: shkerin@mail.ru
Россия, Novosibirsk, 630090
S. Solodovnikov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; National Research Novosibirsk State University
Email: shkerin@mail.ru
Россия, Novosibirsk, 630090; Novosibirsk, 630090
E. Zolotova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: shkerin@mail.ru
Россия, Novosibirsk, 630090
A. Tolkacheva
Institute of High-Temperature Electrochemistry, Ural Branch; Institute of Materials Science and Metallurgy
Email: shkerin@mail.ru
Россия, Yekaterinburg, 620137; Yekaterinburg, 620083
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