Thermolysis characteristics of salts of o-phthalic acid with the formation of Fe, Co, Ni, Cu metal particles
- 作者: Yudanova L.1, Logvinenko V.1,2, Yudanov N.1, Rudina N.3, Ishchenko A.3,2, Korol’kov I.1,2, Semyannikov P.1, Sheludyakova L.1,2, Alferova N.1
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隶属关系:
- Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Institute of Catalysis, Siberian Branch
- 期: 卷 90, 编号 6 (2016)
- 页面: 1206-1211
- 栏目: Physical Chemistry of Nanoclusters and Nanomaterials
- URL: https://journals.rcsi.science/0036-0244/article/view/168328
- DOI: https://doi.org/10.1134/S0036024416060315
- ID: 168328
如何引用文章
详细
Studies of the thermolysis of ortho-[Ni(H2O)2(C8H4O4)](H2O)2, [Cu(H2O)(C8H4O4)], and acid [M(H2O)6](C8H5O4)2 (M(II) = Fe(II), Co(II), and Ni(II)), [Cu(H2O)2(C8H5O4)2] phthalates reveal that the solid products of their decomposition are composites with nanoparticles embedded in carbon–polymer matrices. Metallic nanoparticles with oxide nanoparticle impurities are detected in iron/cobalt polymer composites, while nickel/copper composites are composed of only metallic particles. It is found that nickel nanoparticles with the diameters of 6–8 nm are covered with disordered graphene layers, while the copperbased composite matrix contains spherical conglomerates (50–200 nm) with numerous spherical Cu particles (5–10 nm).
作者简介
L. Yudanova
Institute of Inorganic Chemistry, Siberian Branch
编辑信件的主要联系方式.
Email: judanova@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090
V. Logvinenko
Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: judanova@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090
N. Yudanov
Institute of Inorganic Chemistry, Siberian Branch
Email: judanova@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090
N. Rudina
Institute of Catalysis, Siberian Branch
Email: judanova@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090
A. Ishchenko
Institute of Catalysis, Siberian Branch; Novosibirsk State University
Email: judanova@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090
I. Korol’kov
Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: judanova@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090
P. Semyannikov
Institute of Inorganic Chemistry, Siberian Branch
Email: judanova@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090
L. Sheludyakova
Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: judanova@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090
N. Alferova
Institute of Inorganic Chemistry, Siberian Branch
Email: judanova@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090