Catalytic activity of carbon nanotubes in the conversion of aliphatic alcohols
- 作者: Zhitnev Y.1, Tveritinova E.1, Chernyak S.1, Savilov S.1, Lunin V.1
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隶属关系:
- Department of Chemistry
- 期: 卷 90, 编号 6 (2016)
- 页面: 1128-1131
- 栏目: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/168278
- DOI: https://doi.org/10.1134/S0036024416060327
- ID: 168278
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详细
Carbon nanotubes (CNTs) obtained via the catalytic pyrolysis of hexane at 750°C were studied as the catalysts in conversion of C2–C4 alcohols. The efficiency of CNTs as catalysts in dehydration and dehydrogenation of ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, and tert-butanol was studied by means of pulse microcatalysis. The surface and structural characteristics of CNTs are investigated via SEM, TEM, DTA, BET, and XPS. CNTs are shown to be effective catalysts in the conversion of alcohols and do not require additional oxidative treatment. The regularities of the conversion of aliphatic alcohols, related to the properties of the CNTs surface and the structure of the alcohols are identified.
作者简介
Yu. Zhitnev
Department of Chemistry
编辑信件的主要联系方式.
Email: zhitnevyun@mail.ru
俄罗斯联邦, Moscow, 119991
E. Tveritinova
Department of Chemistry
Email: zhitnevyun@mail.ru
俄罗斯联邦, Moscow, 119991
S. Chernyak
Department of Chemistry
Email: zhitnevyun@mail.ru
俄罗斯联邦, Moscow, 119991
S. Savilov
Department of Chemistry
Email: zhitnevyun@mail.ru
俄罗斯联邦, Moscow, 119991
V. Lunin
Department of Chemistry
Email: zhitnevyun@mail.ru
俄罗斯联邦, Moscow, 119991