Reduction of carbon dioxide by hydrogen on metal–carbon catalysts under supercritical conditions
- Авторы: Bogdan V.I.1,2, Koklin A.E.1, Kozak D.O.1, Kustov L.M.1,2
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Учреждения:
- Zelinsky Institute of Organic Chemistry
- Department of Chemistry
- Выпуск: Том 90, № 12 (2016)
- Страницы: 2352-2357
- Раздел: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/169014
- DOI: https://doi.org/10.1134/S0036024416120050
- ID: 169014
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Аннотация
The reduction of carbon dioxide with hydrogen on metal–carbon (Ru, Rh, Ir) catalysts is investigated under supercritical conditions for the first time. High selectivity (close to 100%) toward methanation with good stability of catalytic activity is observed for Ru- and Rh-containing catalyst, while the preferred reduction to CO is observed for Ir/C catalyst.
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Об авторах
V. Bogdan
Zelinsky Institute of Organic Chemistry; Department of Chemistry
Email: lmk@ioc.ac.ru
Россия, Moscow, 119991; Moscow, 119991
A. Koklin
Zelinsky Institute of Organic Chemistry
Email: lmk@ioc.ac.ru
Россия, Moscow, 119991
D. Kozak
Zelinsky Institute of Organic Chemistry
Email: lmk@ioc.ac.ru
Россия, Moscow, 119991
L. Kustov
Zelinsky Institute of Organic Chemistry; Department of Chemistry
Автор, ответственный за переписку.
Email: lmk@ioc.ac.ru
Россия, Moscow, 119991; Moscow, 119991
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