Kinetics and mechanism of olefin catalytic hydroalumination by organoaluminum compounds
- Авторы: Koledina K.F.1, Gubaidullin I.M.1
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Учреждения:
- Institute of Petrochemistry and Catalysis
- Выпуск: Том 90, № 5 (2016)
- Страницы: 914-921
- Раздел: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/168124
- DOI: https://doi.org/10.1134/S0036024416050186
- ID: 168124
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Аннотация
The complex reaction mechanism of α-olefin catalytic hydroalumination by alkylalanes is investigated via mathematical modeling that involves plotting the kinetic models for the individual reactions that make up a complex system and a separate study of their principles. Kinetic parameters of olefin catalytic hydroalumination are estimated. Activation energies of the possible steps of the schemes of complex reaction mechanisms are compared and possible reaction pathways are determined.
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Об авторах
K. Koledina
Institute of Petrochemistry and Catalysis
Автор, ответственный за переписку.
Email: koledinakamila@mail.ru
Россия, Ufa, 450075
I. Gubaidullin
Institute of Petrochemistry and Catalysis
Email: koledinakamila@mail.ru
Россия, Ufa, 450075
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