Oxidative alkoxylation of phosphine in alcohol solutions of copper halides
- Autores: Polimbetova G.1, Borangazieva A.1, Ibraimova Z.1, Bugubaeva G.1, Keynbay S.1
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Afiliações:
- Sokolskii Institute of Organic Catalysis and Electrochemistry
- Edição: Volume 90, Nº 8 (2016)
- Páginas: 1539-1544
- Seção: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/168558
- DOI: https://doi.org/10.1134/S0036024416080227
- ID: 168558
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Resumo
The phosphine oxidation reaction with oxygen in alcohol solutions of copper (I, II) halides is studied. Kinetic parameters, intermediates, and by-products are studied by means of NMR 31Р-, IR-, UV-, and ESR- spectroscopy; and by magnetic susceptibility, redox potentiometry, gas chromatography, and elemental analysis. A reaction mechanism is proposed, and the optimum conditions are found for the reaction of oxidative alkoxylation phosphine.
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Sobre autores
G. Polimbetova
Sokolskii Institute of Organic Catalysis and Electrochemistry
Autor responsável pela correspondência
Email: zvezda_iju@mail.ru
Cazaquistão, Almaty, 050010
A. Borangazieva
Sokolskii Institute of Organic Catalysis and Electrochemistry
Email: zvezda_iju@mail.ru
Cazaquistão, Almaty, 050010
Zh. Ibraimova
Sokolskii Institute of Organic Catalysis and Electrochemistry
Email: zvezda_iju@mail.ru
Cazaquistão, Almaty, 050010
G. Bugubaeva
Sokolskii Institute of Organic Catalysis and Electrochemistry
Email: zvezda_iju@mail.ru
Cazaquistão, Almaty, 050010
S. Keynbay
Sokolskii Institute of Organic Catalysis and Electrochemistry
Email: zvezda_iju@mail.ru
Cazaquistão, Almaty, 050010