Kinetics and Mechanism of the Oxidative Conversion of n-Amyl Alcohol to Valeric Acid on a Modified Zeolite Catalyst
- Авторлар: Aliev A.1, Bakhmanov M.1, Agaev F.1, Agaev V.1, Shabanova Z.1, Safarov A.1
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Мекемелер:
- Nagiev Institute of Catalysis and Inorganic Chemistry
- Шығарылым: Том 92, № 4 (2018)
- Беттер: 656-662
- Бөлім: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/169954
- DOI: https://doi.org/10.1134/S0036024418040027
- ID: 169954
Дәйексөз келтіру
Аннотация
The catalytic activity of natural and synthetic mordenites modified with Cu2+, Zn2+, and Pd2+ cations via ion exchange was studied in the oxidative conversion of n-amyl alcohol to valeric acid under the action of oxygen. It is established that the highest activity and selectivity in this reaction is exhibited by mordenite hydrothermally synthesized from kaolinite and containing 3.0 wt % Cu2+, 0.1 wt % Pd2+, and 2.0 wt % Zn2+. The kinetics of this catalytic reaction is studied. Based on the experimental data, a possible stepwise mechanism is proposed, and a theoretically grounded kinetic model of the process is developed.
Негізгі сөздер
Авторлар туралы
A. Aliev
Nagiev Institute of Catalysis and Inorganic Chemistry
Хат алмасуға жауапты Автор.
Email: agil_s@mail.ru
Әзірбайжан, Baku, AZ1143
M. Bakhmanov
Nagiev Institute of Catalysis and Inorganic Chemistry
Email: agil_s@mail.ru
Әзірбайжан, Baku, AZ1143
F. Agaev
Nagiev Institute of Catalysis and Inorganic Chemistry
Email: agil_s@mail.ru
Әзірбайжан, Baku, AZ1143
V. Agaev
Nagiev Institute of Catalysis and Inorganic Chemistry
Email: agil_s@mail.ru
Әзірбайжан, Baku, AZ1143
Z. Shabanova
Nagiev Institute of Catalysis and Inorganic Chemistry
Email: agil_s@mail.ru
Әзірбайжан, Baku, AZ1143
A. Safarov
Nagiev Institute of Catalysis and Inorganic Chemistry
Email: agil_s@mail.ru
Әзірбайжан, Baku, AZ1143