Complexation equilibria in tetrahydrofuran solutions of palladium(II) and lithium bromides
- Авторлар: Putin A.1, Katsman E.1, Temkin O.1, Bruk L.1
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Мекемелер:
- Moscow Technological University
- Шығарылым: Том 91, № 4 (2017)
- Беттер: 697-707
- Бөлім: Structure of Matter and Quantum Chemistry
- URL: https://journals.rcsi.science/0036-0244/article/view/169410
- DOI: https://doi.org/10.1134/S0036024417040227
- ID: 169410
Дәйексөз келтіру
Аннотация
The solutions of palladium PdBr2 and lithium LiBr bromides in tetrahydrofuran (THF) at different concentrations were studied by UV–Vis spectroscopy. The data obtained were mathematically processed using various models. The best description was obtained with the model that includes the formation of four monomeric (PdBr+, PdBr2, PdBr3-, PdBr42-) and three dimeric (Pd2Br22+, Pd2Br4, Pd2Br62-) palladium complexes. The equilibrium constants of the monomer and dimer complexation stages and the extinction coefficients of the palladium complexes were calculated. The spectra of the individual monomer and dimer palladium complexes were calculated using this model.
Авторлар туралы
A. Putin
Moscow Technological University
Хат алмасуға жауапты Автор.
Email: putinalekse@yandex.ru
Ресей, Moscow, 119454
E. Katsman
Moscow Technological University
Email: putinalekse@yandex.ru
Ресей, Moscow, 119454
O. Temkin
Moscow Technological University
Email: putinalekse@yandex.ru
Ресей, Moscow, 119454
L. Bruk
Moscow Technological University
Email: putinalekse@yandex.ru
Ресей, Moscow, 119454