Selective determination of rate constants of reactions of atomic hydrogen with various functional groups of a complex molecule
- Authors: Brauer G.B.1, Pugachev D.V.1, Azatyan V.V.1
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Affiliations:
- Institute of Structural Macrokinetics and Materials Science
- Issue: Vol 90, No 5 (2016)
- Pages: 922-925
- Section: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/168129
- DOI: https://doi.org/10.1134/S0036024416050101
- ID: 168129
Cite item
Abstract
The possibility of determining absolute values of the rate constants of reactions of active intermediate species with different functional groups of molecules is demonstrated by measuring macrokinetic combustion characteristics. The Arrhenius parameters of the rate constant of the reaction between atomic hydrogen with the methylene group of ethanol and molecular oxygen within the temperature range of 830–970 K are determined. The reasons for the differences between the rate constants of reactions with the methylene and methyl groups of an ethanol molecule are discussed using thermochemical data. It is found that the obtained values of activation energies and preexponential factors of rate constants are in good agreement with the literature data on the region of lower temperatures.
About the authors
G. B. Brauer
Institute of Structural Macrokinetics and Materials Science
Author for correspondence.
Email: gbr@ism.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
D. V. Pugachev
Institute of Structural Macrokinetics and Materials Science
Email: gbr@ism.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
V. V. Azatyan
Institute of Structural Macrokinetics and Materials Science
Email: gbr@ism.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432