Extraction of Cobalt(II) from Sulfate Medium with Substituted Salicylideneanilines


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Abstract

The liquid-liquid extraction of cobalt(II) from sulfate media (Na2SO4) with substituted salicylideneanilines (SAN) is investigated. The stoichiometry of the extracted complexes formed in the organic phase is evaluated. It was found that the cobalt is coordinated with three ligands (L), and composition of the extracted complex is: CoL2HL and cobalt is coordinated with two ligands (L) in case of substituted SA as CoL2. The values of the extraction constants were calculated and analyzed in terms of the nature of the substituents.

About the authors

Yamina Boukraa

Département de Chimie Organique Industrielle, Faculté de Chimie, Université des Sciences et de la Technologie d’Oran, M’Nouar

Author for correspondence.
Email: boukraa.yamina@yahoo.fr
Algeria, Oran, BP 1505

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