Ethylene Conversion over Catalysts Based on Solid Superacids and Heteropoly Acids
- Authors: Tarasov A.L.1
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Affiliations:
- Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Issue: Vol 92, No 11 (2018)
- Pages: 2139-2142
- Section: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/170192
- DOI: https://doi.org/10.1134/S0036024418110407
- ID: 170192
Cite item
Abstract
Catalytic properties of solid superacids (WO3/ZrO2 and SO4/ZrO2), and monolith and H-Beta zeolite-supported phosphotungstic heteropoly acid in gas-phase alkylation of benzene with ethylene to ethylbenzene and in the side reaction of ethylene oligomerization are studied. It was found that H-Beta zeolite had the highest activity and selectivity to ethylbenzene. The use of solid superacid (WO3/ZrO2) was shown to be more efficient in low-temperature oligomerization of ethylene.
Keywords
About the authors
A. L. Tarasov
Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: atarasov@ioc.ac.ru
Russian Federation, Moscow
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