Ethylene Conversion over Catalysts Based on Solid Superacids and Heteropoly Acids


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Abstract

Catalytic properties of solid superacids (WO3/ZrO2 and SO4/ZrO2), and monolith and H-Beta zeolite-supported phosphotungstic heteropoly acid in gas-phase alkylation of benzene with ethylene to ethylbenzene and in the side reaction of ethylene oligomerization are studied. It was found that H-Beta zeolite had the highest activity and selectivity to ethylbenzene. The use of solid superacid (WO3/ZrO2) was shown to be more efficient in low-temperature oligomerization of ethylene.

About the authors

A. L. Tarasov

Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: atarasov@ioc.ac.ru
Russian Federation, Moscow

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