Thermodynamic Properties of Tl9GdTe6 and TlGdTe2


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Abstract

The results of a thermodynamic study of the Tl2Te–Tl2Te3–TlGdTe2 system by the electromotive force (EMF) method in the temperature range 300–450 K were presented. The partial thermodynamic functions of GdTe and Gd in alloys were first determined from the experimental EMF data for concentration cells relative to the GdTe electrode. The standard thermodynamic functions of formation and standard entropies of Tl9GdTe6 and TlGdTe2 were calculated based on these data.

About the authors

S. Z. Imamaliyeva

Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan

Author for correspondence.
Email: samira9597a@gmail.com
Azerbaijan, Baku

D. M. Babanly

Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan

Email: samira9597a@gmail.com
Azerbaijan, Baku

T. M. Gasanly

Baku State University

Email: samira9597a@gmail.com
Azerbaijan, Baku

D. B. Tagiyev

Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan

Email: samira9597a@gmail.com
Azerbaijan, Baku

M. B. Babanly

Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan

Email: samira9597a@gmail.com
Azerbaijan, Baku


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