Thermodynamics of the Formation of Complexes of Nickel(II), Triglycine, and L-Histidine in Aqueous Solutions


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Abstract

The Ni2+–triglycine–L-histidine system is studied by potentiometric and calorimetric means in aqueous solutions at Т = 298.15 K (KNO3). The formation of mixed ligand complex NiLY is registered, and standard thermodynamic characteristics (ΔrH°, ΔrG°, ΔrS°) of its formation are determined. A structure of the complex is proposed.

About the authors

G. G. Gorboletova

Ivanovo State University of Chemistry and Technology

Author for correspondence.
Email: gorboletova@mail.ru
Russian Federation, Ivanovo, 153000

A. A. Metlin

Ivanovo State University of Chemistry and Technology

Email: gorboletova@mail.ru
Russian Federation, Ivanovo, 153000

S. A. Bychkova

Ivanovo State University of Chemistry and Technology

Email: gorboletova@mail.ru
Russian Federation, Ivanovo, 153000


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