Hydration and dielectrical properties of aqueous pyrrolidinium trifluoroacetate solutions
- Authors: Lyashchenko A.K.1, Balakaeva I.V.1, Simonova Y.A.2, Timofeeva L.M.2
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- Topchiev Institute of Petrochemical Synthesis
- Issue: Vol 91, No 10 (2017)
- Pages: 1913-1918
- Section: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0244/article/view/169724
- DOI: https://doi.org/10.1134/S0036024417100247
- ID: 169724
Cite item
Abstract
Results from microwave measurements of the dielectrical properties of aqueous pyrrolidinium trifluoroacetate solutions at maximum water dispersion frequencies (13–25 GHz) and temperatures of 288, 298, and 308 K are given. The static dielectrical constants, times, and activation parameters of the dielectrical relaxation of solutions are calculated. The enthalpy and time of dielectrical relaxation activation are increased by deceleration of the motion of water molecules in the hydrate shells of ions. The changes in dielectrical parameters are in this case minimal in a series of aqueous solutions of diallylammonium salts with cations of different structures and degrees of substitution. It is shown that pyrrolidinium ions are characterized by weak hydrophobic hydration.
About the authors
A. K. Lyashchenko
Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: aklyas@mail.ru
Russian Federation, Moscow, 119991
I. V. Balakaeva
Kurnakov Institute of General and Inorganic Chemistry
Email: aklyas@mail.ru
Russian Federation, Moscow, 119991
Yu. A. Simonova
Topchiev Institute of Petrochemical Synthesis
Email: aklyas@mail.ru
Russian Federation, Moscow, 119991
L. M. Timofeeva
Topchiev Institute of Petrochemical Synthesis
Email: aklyas@mail.ru
Russian Federation, Moscow, 119991