Polar stationary phases based on poly(oligo ethylene glycol)diacrylates for capillary gas chromatography
- Authors: Shiryaeva V.E.1, Popova T.P.1, Korolev A.A.1, Kanat’eva A.Y.1, Kurganov A.A.1
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Affiliations:
- Topchiev Institute of Petrochemical Synthesis
- Issue: Vol 91, No 8 (2017)
- Pages: 1571-1579
- Section: Physical Chemistry of Separation Processes. Chromatography
- URL: https://journals.rcsi.science/0036-0244/article/view/169675
- DOI: https://doi.org/10.1134/S0036024417080325
- ID: 169675
Cite item
Abstract
New stationary phases for capillary columns in GC are synthesized and studied. The phases are prepared by depositing oligo(ethylene glycol)diacrylates on the column walls and subsequent polymerization (crosslinking) in the presence of peroxide initiators. It is shown that stationary phases based on monomers with molecular weights of 10 kDa or higher exhibit separation properties similar to those of conventional stationary phases based on polyethylene glycol (PEG); however, their thermal stability is higher because they have a higher degree of crosslinking and a more ordered structure of the crosslinked polymers than the respective parameters of phases based on native PEG.
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About the authors
V. E. Shiryaeva
Topchiev Institute of Petrochemical Synthesis
Author for correspondence.
Email: shiryeva@ips.ac.ru
Russian Federation, Moscow, 119991
T. P. Popova
Topchiev Institute of Petrochemical Synthesis
Email: shiryeva@ips.ac.ru
Russian Federation, Moscow, 119991
A. A. Korolev
Topchiev Institute of Petrochemical Synthesis
Email: shiryeva@ips.ac.ru
Russian Federation, Moscow, 119991
A. Yu. Kanat’eva
Topchiev Institute of Petrochemical Synthesis
Email: shiryeva@ips.ac.ru
Russian Federation, Moscow, 119991
A. A. Kurganov
Topchiev Institute of Petrochemical Synthesis
Email: shiryeva@ips.ac.ru
Russian Federation, Moscow, 119991