Thermodynamic functions of arsenic selenides


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Abstract

The solid-phase equilibria and thermodynamic properties of an As–Se system are studied using the electromotive force (EMF). The existence of compounds As2Se3, AsSe, and As4Se3 in a system with near constant composition is confirmed. The relative partial molar functions, standard Gibbs free energies, enthalpies of formation, and standard entropies of As in the alloys are calculated using EMF measurements.

About the authors

D. M. Babanly

Baku Institute of Catalysis and Inorganic Chemistry

Author for correspondence.
Email: Babanly_mb@rambler.ru
Azerbaijan, Baku, 1143

G. M. Velieva

Baku State University

Email: Babanly_mb@rambler.ru
Azerbaijan, Baku, 1148

S. Z. Imamaliyeva

Baku Institute of Catalysis and Inorganic Chemistry

Email: Babanly_mb@rambler.ru
Azerbaijan, Baku, 1143

M. B. Babanly

Baku Institute of Catalysis and Inorganic Chemistry

Email: Babanly_mb@rambler.ru
Azerbaijan, Baku, 1143

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