Effect of temperature on the adsorption of phosphatidylcholine by silicon-containing materials with various degrees of order
- Authors: Askurava A.S.1, Sinyaeva L.A.1, Belanova N.A.1, Karpov S.I.1, Selemenev V.F.1, Roessner F.2
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Affiliations:
- Department of Chemistry
- Chemical Technology II, Institute of Chemistry, Department of Mathematics and Natural Sciences
- Issue: Vol 91, No 6 (2017)
- Pages: 1121-1126
- Section: Physical Chemistry of Surface Phenomena
- URL: https://journals.rcsi.science/0036-0244/article/view/169556
- DOI: https://doi.org/10.1134/S0036024417060024
- ID: 169556
Cite item
Abstract
Features of the adsorption of phosphatidylcholine (PCh) by inorganic silicon-containing materials with various degrees of order (MCM-41, MMC-1, and silica gel) from solutions in hexane under equilibrium conditions in the temperature range of 283–323 K are considered. It is found that the adsorption of the phospholipid within the Ce = (0.6–4.0) × 10–4 mmol/dm3 range of concentrations on the investigated materials is characterized by monomolecular absorption. Differential thermodynamic characteristics (ΔG, ΔH, and ΔS) of the sorption of PCh by silicon-containing materials with various degrees of order in the temperature range of 283–323 K are considered. An increase in the affinity of silicon-containing materials toward the phospholipid upon an increase in the temperature of the sorption process is observed.
Keywords
About the authors
A. S. Askurava
Department of Chemistry
Email: belanovana@mail.ru
Russian Federation, Voronezh, 394018
L. A. Sinyaeva
Department of Chemistry
Email: belanovana@mail.ru
Russian Federation, Voronezh, 394018
N. A. Belanova
Department of Chemistry
Author for correspondence.
Email: belanovana@mail.ru
Russian Federation, Voronezh, 394018
S. I. Karpov
Department of Chemistry
Email: belanovana@mail.ru
Russian Federation, Voronezh, 394018
V. F. Selemenev
Department of Chemistry
Email: belanovana@mail.ru
Russian Federation, Voronezh, 394018
F. Roessner
Chemical Technology II, Institute of Chemistry, Department of Mathematics and Natural Sciences
Email: belanovana@mail.ru
Germany, Oldenburg, D-26111