Thermodynamics of reactions of complex formation for Ce3+ and Er3+ ions with glycine in an aqueous solution


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Abstract

Enthalpies of complex formation for glycine (HL±) with Ce3+ and Er3+ ions at 298.15 K and the value of the ionic strength of 0.5 (KNO3) are determined by calorimetric means using two independent procedures. Thermodynamic characteristics of the reactions of formation for complexes of glycine with Ce3+ and Er3+ ions at various [metal]: [ligand] molar ratios are calculated.

About the authors

A. I. Lytkin

Ivanovo State University of Chemistry and Technology

Author for correspondence.
Email: kdvkonkpd@dsn.ru
Russian Federation, Ivanovo, 153000

V. V. Chernikov

Ivanovo State University of Chemistry and Technology

Email: kdvkonkpd@dsn.ru
Russian Federation, Ivanovo, 153000

O. N. Krutova

Ivanovo State University of Chemistry and Technology

Email: kdvkonkpd@dsn.ru
Russian Federation, Ivanovo, 153000

I. A. Skvortsov

Ivanovo State University of Chemistry and Technology

Email: kdvkonkpd@dsn.ru
Russian Federation, Ivanovo, 153000


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