Oxidation of ethanol on NaX zeolite modified with transition metals
- 作者: Mirzai J.I.1, Nadirov P.A.1, Velieva A.D.1, Muradkhanli V.G.1
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隶属关系:
- Azerbaijan State Oil and Industrial University
- 期: 卷 91, 编号 6 (2017)
- 页面: 1005-1009
- 栏目: Chemical Thermodynamics and Thermochemistry
- URL: https://journals.rcsi.science/0036-0244/article/view/169517
- DOI: https://doi.org/10.1134/S0036024417060164
- ID: 169517
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详细
NaLaX, NaX + Co, and NaPdX catalysts are synthesized by modification of NaX zeolite with transition metals (La, Co, Pd). The activity of the prepared materials in catalytic ethanol oxidation is studied in the temperature range of 423–723 K. It is shown that NaPdX and NaX + Co accelerate the reactions of partial and complete oxidation of ethanol as the temperature rises. NaLaX accelerates both intramolecular and intermolecular dehydration of alcohol. It is shown that the NaPdX (1.0% Pd) sample has the highest activity in the complete oxidation of alcohol with the formation of CO2.
作者简介
J. Mirzai
Azerbaijan State Oil and Industrial University
Email: parviznadirov@rambler.ru
阿塞拜疆, Baku, AZ100
P. Nadirov
Azerbaijan State Oil and Industrial University
编辑信件的主要联系方式.
Email: parviznadirov@rambler.ru
阿塞拜疆, Baku, AZ100
A. Velieva
Azerbaijan State Oil and Industrial University
Email: parviznadirov@rambler.ru
阿塞拜疆, Baku, AZ100
V. Muradkhanli
Azerbaijan State Oil and Industrial University
Email: parviznadirov@rambler.ru
阿塞拜疆, Baku, AZ100
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