Interfacial tension in cooled heterogeneous liquid acetonitrile–ethyl acetate–isopropanol–water–phenol systems


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Abstract

It is found that the tension at the interfacial boundary of liquid phases formed by mixtures of acetonitrile–ethyl acetate–isopropanol (85 : 15 : 0 and 80 : 15 : 5 vol/vol/vol %) and water at 263 K falls exponentially as the concentration of phenols grows within 0–1 mg/mL. It is shown that the relatively low values of interfacial tension (11–32 mN/m) observed in cooled heterogeneous systems promote the redistribution of phenols between two liquid phases.

About the authors

O. B. Rudakov

Voronezh State University of Architecture and Civil Engineering

Author for correspondence.
Email: robi57@mail.ru
Russian Federation, Voronezh, 394006

E. A. Khorokhordina

Voronezh State University of Architecture and Civil Engineering

Email: robi57@mail.ru
Russian Federation, Voronezh, 394006

M. A. Preobrazhenskii

Voronezh State University of Architecture and Civil Engineering

Email: robi57@mail.ru
Russian Federation, Voronezh, 394006

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