Interfacial tension in cooled heterogeneous liquid acetonitrile–ethyl acetate–isopropanol–water–phenol systems
- Authors: Rudakov O.B.1, Khorokhordina E.A.1, Preobrazhenskii M.A.1
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Affiliations:
- Voronezh State University of Architecture and Civil Engineering
- Issue: Vol 91, No 4 (2017)
- Pages: 754-757
- Section: Physical Chemistry of Surface Phenomena
- URL: https://journals.rcsi.science/0036-0244/article/view/169426
- DOI: https://doi.org/10.1134/S0036024417040240
- ID: 169426
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Abstract
It is found that the tension at the interfacial boundary of liquid phases formed by mixtures of acetonitrile–ethyl acetate–isopropanol (85 : 15 : 0 and 80 : 15 : 5 vol/vol/vol %) and water at 263 K falls exponentially as the concentration of phenols grows within 0–1 mg/mL. It is shown that the relatively low values of interfacial tension (11–32 mN/m) observed in cooled heterogeneous systems promote the redistribution of phenols between two liquid phases.
About the authors
O. B. Rudakov
Voronezh State University of Architecture and Civil Engineering
Author for correspondence.
Email: robi57@mail.ru
Russian Federation, Voronezh, 394006
E. A. Khorokhordina
Voronezh State University of Architecture and Civil Engineering
Email: robi57@mail.ru
Russian Federation, Voronezh, 394006
M. A. Preobrazhenskii
Voronezh State University of Architecture and Civil Engineering
Email: robi57@mail.ru
Russian Federation, Voronezh, 394006
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