Quantum chemical study of the rearrangement of phenoxyl-hydroxyphenyl radicals

V. I. Porkhun; Yu. V. Aristova; E. V. Porkhun

doi:10.1134/S0036024417030220

Quantum chemical study of the rearrangement of phenoxyl-hydroxyphenyl radicals

作者: Porkhun V.I.¹, Aristova Y.V.¹, Porkhun E.V.¹
隶属关系:
1. Volgograd State Technical University
期: 卷 91, 编号 3 (2017)
页面: 472-475
栏目: Chemical Kinetics and Catalysis
URL: https://journals.rcsi.science/0036-0244/article/view/169318
DOI: https://doi.org/10.1134/S0036024417030220
ID: 169318

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The absorption spectra and decomposition kinetics of intermediates formed upon the photolysis of p-iodophenol are studied via flash photolysis. The extinction coefficient of the p-iodophenoxyl radical is calculated. It is found that p-iodophenol acts as an inhibitor of light-independent liquid-phase oxidation reactions.