Effect of pluronic P123 on the distribution of nanodiamond particles in water–organic liquid systems

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Abstract

The effect adsorption layers of nonionic surfactant (pluronic P123) have on the distribution of nanodiamonds (NDs) between aqueous and organic phases is studied with radioactive tracers using compounds labeled with tritium. The values of reversible and irreversible adsorptions of P123 on NDs are determined. It is shown that the distribution coefficients of NDs modified by irreversibly adsorbed layers of P123 are several times higher than those of raw nanodiamonds. This result is explained by the hydrophobization of an ND’s surface, as is shown by data obtained via interfacial tensiometry and wetting.

About the authors

O. A. Soboleva

Department of Chemistry

Author for correspondence.
Email: Oxana_Soboleva@mail.ru
Russian Federation, Moscow, 119991

M. G. Chernysheva

Department of Chemistry

Email: Oxana_Soboleva@mail.ru
Russian Federation, Moscow, 119991

I. Yu. Myasnikov

Department of Chemistry

Email: Oxana_Soboleva@mail.ru
Russian Federation, Moscow, 119991

V. A. Kostin

Department of Chemistry

Email: Oxana_Soboleva@mail.ru
Russian Federation, Moscow, 119991

G. A. Badun

Department of Chemistry

Email: Oxana_Soboleva@mail.ru
Russian Federation, Moscow, 119991


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