Relationship between the catalytic properties of the products of the oxidative thermolysis of certain complexes and the porous structures of samples in the oxidation reactions of volatile organic compounds
- Authors: Semushina Y.P.1, Pechenyuk S.I.1, Kuzmich L.F.1, Knyazeva A.I.1
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Affiliations:
- Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials
- Issue: Vol 91, No 1 (2017)
- Pages: 26-29
- Section: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/169157
- DOI: https://doi.org/10.1134/S003602441701023X
- ID: 169157
Cite item
Abstract
The rate of the gas-phase oxidation of ethanol, 2-propanol, acetone, ethyl acetate, dioxane, and benzene with atmospheric oxygen is studied on surfaces of bimetallic oxide catalysts Co–Fe, Cu–Fe, Cr–Co, and Ni–Fe, prepared via thermal decomposition of double complex compounds in air. It is found that the rate of oxidation of volatile compounds depends on the volume of the transient pores in the catalyst sample. The rate of oxidation on the same catalyst at 350°C depends on the nature of the substance in the order: acetone > ethyl acetate > ethanol > propanol > dioxane, benzene.
About the authors
Yu. P. Semushina
Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials
Email: pechenyuk@chemy.kolasc.net.ru
Russian Federation, Apatity, 184209
S. I. Pechenyuk
Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials
Author for correspondence.
Email: pechenyuk@chemy.kolasc.net.ru
Russian Federation, Apatity, 184209
L. F. Kuzmich
Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials
Email: pechenyuk@chemy.kolasc.net.ru
Russian Federation, Apatity, 184209
A. I. Knyazeva
Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials
Email: pechenyuk@chemy.kolasc.net.ru
Russian Federation, Apatity, 184209