Email this article Efficient Generation of Chemiluminescence during the reduction of manganese(IV) ions with lactic acid
- Authors: Tsaplev Y.B.1,2
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Affiliations:
- Emanuel Institute of Biochemical Physics
- Semenov Institute of Chemical Physics
- Issue: Vol 90, No 12 (2016)
- Pages: 2481-2487
- Section: Photochemistry and Magnetochemistry
- URL: https://journals.rcsi.science/0036-0244/article/view/169076
- DOI: https://doi.org/10.1134/S0036024416120311
- ID: 169076
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Abstract
The kinetics and mechanism of chemiluminescence during the reduction of manganese(IV) ions with lactic acid in an H2SO4–AcOH medium are studied. Kinetic spectrophotometric measurements are used to determine the profiles of change in the concentrations of Mn(IV) and Mn(III) ions during the reaction. The results from kinetic spectrophotometric measurements are compared to the light yield kinetics. The quantum chemiluminescence and chemiexcitation yields reach record values.
About the authors
Yu. B. Tsaplev
Emanuel Institute of Biochemical Physics; Semenov Institute of Chemical Physics
Author for correspondence.
Email: tsap_04@mail.ru
Russian Federation, Moscow, 119991; Moscow, 119991
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