Catalytic properties of CexZr1–xO2 prepared using a template in the oxidation of CO
- Authors: Kaplin I.Y.1,2, Lokteva E.S.1,2, Golubina E.V.1,2, Maslakov K.I.1,2, Chernyak S.A.1, Levanov A.V.1, Strokova N.E.1,2, Lunin V.V.1
-
Affiliations:
- Department of Chemistry
- Institute of Hydrocarbons Processing
- Issue: Vol 90, No 11 (2016)
- Pages: 2157-2164
- Section: Chemical Kinetics and Catalysis
- URL: https://journals.rcsi.science/0036-0244/article/view/168926
- DOI: https://doi.org/10.1134/S0036024416110108
- ID: 168926
Cite item
Abstract
The catalytic activity in CO oxidation of CexZr1–xO2 double oxides prepared using pine sawdust and cetyltrimethylammonium bromide (CTAB) as templates is compared. It is found by means of SEM and the low-temperature adsorption of N2 that biomorphic oxides reproduce the macropore structure of the template. It is shown via XRD and Raman spectroscopy that all samples contained mixed ceria-zirconia oxide. The double oxides form a cubic phase with a lattice of the fluorite type at a ratio of Ce: Zr = 4, regardless of the nature of the template; when Ce: Zr = 1, the biomorphic mixed oxide forms a tetragonal phase. According to Raman spectroscopy and XRD it was shown that the distortion of the oxygen sublattice is higher in biomorphic samples. Energy dispersive analysis shows that Ca impurities were present in the biomorphic samples, introducing additional distortions in the lattice of double oxide and leading to the formation of anionic vacancies. It is found that when Ce: Zr = 4, the conversion of CO on biomorphic oxide in the range of 100–350°C is higher than that observed for CexZr1–xO2 (CTAB); reducing the Ce: Zr ratio in the biomorphic sample to 1 results in a marked decrease in CO conversion at 100–200°C. It is concluded that these differences are due to changes in the mobility of the lattice oxygen.
About the authors
I. Yu. Kaplin
Department of Chemistry; Institute of Hydrocarbons Processing
Author for correspondence.
Email: kaplinigormsu@gmail.com
Russian Federation, Moscow, 119991; Omsk, 644040
E. S. Lokteva
Department of Chemistry; Institute of Hydrocarbons Processing
Email: kaplinigormsu@gmail.com
Russian Federation, Moscow, 119991; Omsk, 644040
E. V. Golubina
Department of Chemistry; Institute of Hydrocarbons Processing
Email: kaplinigormsu@gmail.com
Russian Federation, Moscow, 119991; Omsk, 644040
K. I. Maslakov
Department of Chemistry; Institute of Hydrocarbons Processing
Email: kaplinigormsu@gmail.com
Russian Federation, Moscow, 119991; Omsk, 644040
S. A. Chernyak
Department of Chemistry
Email: kaplinigormsu@gmail.com
Russian Federation, Moscow, 119991
A. V. Levanov
Department of Chemistry
Email: kaplinigormsu@gmail.com
Russian Federation, Moscow, 119991
N. E. Strokova
Department of Chemistry; Institute of Hydrocarbons Processing
Email: kaplinigormsu@gmail.com
Russian Federation, Moscow, 119991; Omsk, 644040
V. V. Lunin
Department of Chemistry
Email: kaplinigormsu@gmail.com
Russian Federation, Moscow, 119991