Isobaric vapor liquid equilibria data for the binary system (glycidyl butyrate + acetone, glycidyl butyrate + carbon tetrachloride, glycidyl butyrate + chloroform) at atmospheric pressure 101 kPa
- Authors: Huang Q.1, Meng Q.1,2, Ban C.1, Zhang R.1, Gao Y.1
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Affiliations:
- School of Chemical Engineering and Energy
- Luoyang Yonglong Energy and Chemical Co.
- Issue: Vol 90, No 9 (2016)
- Pages: 1789-1797
- Section: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0244/article/view/168723
- DOI: https://doi.org/10.1134/S0036024416090260
- ID: 168723
Cite item
Abstract
Isobaric vapor liquid equilibria (VLE) for the binary mixtures of glycidyl butyrate(1) + acetone(2), glycidyl butyrate(1) + carbon tetrachloride(2) and glycidyl butyrate(1) + chloroform(2) at 101 kPa were studied. The experimental data were satisfactorily correlated with the models of Wilson, NRTL and UNIQUAC activity coefficients. The activity coefficients for the equilibrium data were obtained by the nonlinear least square method. The average relative deviations between experimental temperatures and calculated temperatures by the Wilson, NRTL and UNIQUAC models were 0.16, 0.16, 0.23% for glycidyl butyrate(1) + chloroform( 2), 0.38, 0.12, 0.27% for glycidylbutyrate(1) + carbon tetrachloride(2), and 0.67, 0.13, 0.54% for glycidyl butyrate(1) + acetone(2). Azeotrope behavior was not found for these systems. The thermodynamic consistency of the correlations was checked by the Herrington’s area test.
Keywords
About the authors
Qiang Huang
School of Chemical Engineering and Energy
Email: mengqingyi2009@sina.com
China, Zhengzhou, Henan, 450001
Qingyi Meng
School of Chemical Engineering and Energy; Luoyang Yonglong Energy and Chemical Co.
Author for correspondence.
Email: mengqingyi2009@sina.com
China, Zhengzhou, Henan, 450001; Luoyang, 471100
Chunlan Ban
School of Chemical Engineering and Energy
Email: mengqingyi2009@sina.com
China, Zhengzhou, Henan, 450001
Rui Zhang
School of Chemical Engineering and Energy
Email: mengqingyi2009@sina.com
China, Zhengzhou, Henan, 450001
Yingyu Gao
School of Chemical Engineering and Energy
Email: mengqingyi2009@sina.com
China, Zhengzhou, Henan, 450001
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