Isobaric vapor liquid equilibria data for the binary system (glycidyl butyrate + acetone, glycidyl butyrate + carbon tetrachloride, glycidyl butyrate + chloroform) at atmospheric pressure 101 kPa


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Abstract

Isobaric vapor liquid equilibria (VLE) for the binary mixtures of glycidyl butyrate(1) + acetone(2), glycidyl butyrate(1) + carbon tetrachloride(2) and glycidyl butyrate(1) + chloroform(2) at 101 kPa were studied. The experimental data were satisfactorily correlated with the models of Wilson, NRTL and UNIQUAC activity coefficients. The activity coefficients for the equilibrium data were obtained by the nonlinear least square method. The average relative deviations between experimental temperatures and calculated temperatures by the Wilson, NRTL and UNIQUAC models were 0.16, 0.16, 0.23% for glycidyl butyrate(1) + chloroform( 2), 0.38, 0.12, 0.27% for glycidylbutyrate(1) + carbon tetrachloride(2), and 0.67, 0.13, 0.54% for glycidyl butyrate(1) + acetone(2). Azeotrope behavior was not found for these systems. The thermodynamic consistency of the correlations was checked by the Herrington’s area test.

About the authors

Qiang Huang

School of Chemical Engineering and Energy

Email: mengqingyi2009@sina.com
China, Zhengzhou, Henan, 450001

Qingyi Meng

School of Chemical Engineering and Energy; Luoyang Yonglong Energy and Chemical Co.

Author for correspondence.
Email: mengqingyi2009@sina.com
China, Zhengzhou, Henan, 450001; Luoyang, 471100

Chunlan Ban

School of Chemical Engineering and Energy

Email: mengqingyi2009@sina.com
China, Zhengzhou, Henan, 450001

Rui Zhang

School of Chemical Engineering and Energy

Email: mengqingyi2009@sina.com
China, Zhengzhou, Henan, 450001

Yingyu Gao

School of Chemical Engineering and Energy

Email: mengqingyi2009@sina.com
China, Zhengzhou, Henan, 450001

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