Electrical conductivity of solutions of copper(II) nitrate crystalohydrate in dimethyl sulfoxide


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Abstract

Conductometry is used to investigate the electric conductivity of Cu(NO3)2 ⋅ 3Н2О solutions in dimethyl sulfoxide in the 0.01–2.82 M range of concentrations and at temperatures of 288–318 K. The limiting molar conductivity of the electrolyte and the mobility of Cu2+ and NO3- ions, the effective coefficients of diffusion of copper(II) ions and nitrate ions, and the degree and constant of electrolytic dissociation are calculated for different temperatures from the experimental results. It is established that solutions containing 0.1–0.6 M copper nitrate trihydrate in DMSO having low viscosity and high electrical conductivity can be used in electrochemical deposition.

About the authors

Aigul K. Mamyrbekova

Higher School of Chemical Engineering and Biotechnology

Author for correspondence.
Email: aigul_akm@mail.ru
Kazakhstan, Shymkent, 160012

A. D. Mamitova

Higher School of Chemical Engineering and Biotechnology

Email: aizhan_akm@mail.ru
Kazakhstan, Shymkent, 160012

Aizhan K. Mamyrbekova

Faculty of Medicine

Author for correspondence.
Email: aizhan_akm@mail.ru
Kazakhstan, Turkistan


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