Thermodynamic characteristics of sorption extraction and chromatographic separation of anionic complexes of erbium and cerium with Trilon B on weakly basic anionite
- Authors: Cheremisina O.V.1, Ponomareva M.A.1, Sagdiev V.N.1
-
Affiliations:
- National Mineral Resources (Mining) University
- Issue: Vol 90, No 3 (2016)
- Pages: 664-670
- Section: Physical Chemistry of Separation Processes: Chromatography
- URL: https://journals.rcsi.science/0036-0244/article/view/167948
- DOI: https://doi.org/10.1134/S0036024416030079
- ID: 167948
Cite item
Abstract
The adsorption of anionic complexes of erbium with Trilon B on D-403 anionite is studied at ionic strengths of 1 and 2 mol/kg (NaNO3) and temperatures of 298 and 343 K. The values of the stability constants of complex ions of REE with Trilon B and the Gibbs energies of complexation are calculated. The values of the Gibbs energy and the enthalpy and entropy of ion exchange are determined. Using the obtained thermo-dynamic and sorption characteristics, the possible separation of anionic complexes of erbium and cerium with Trilon B is demonstrated via frontal ion-exchange chromatography. A series of sorption capacities of anionic complexes of cerium, yttrium, and erbium is presented using the values of the Gibbs energy of ion exchange.
About the authors
O. V. Cheremisina
National Mineral Resources (Mining) University
Author for correspondence.
Email: ovcheremisina@yandex.ru
Russian Federation, St. Petersburg, 199106
M. A. Ponomareva
National Mineral Resources (Mining) University
Email: ovcheremisina@yandex.ru
Russian Federation, St. Petersburg, 199106
V. N. Sagdiev
National Mineral Resources (Mining) University
Email: ovcheremisina@yandex.ru
Russian Federation, St. Petersburg, 199106