Thermodynamics of thiourea dissolution in methanol–water mixtures


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The solubilities of thiourea in methanol-water mixtures with mass fraction of methanol of 0.54, 0.65, 0.76, 0.88, and 1.00 were determined. The experimental data were approximated with the modified Apelblat equation. The dissolution enthalpy and entropy were calculated from the experimental data and the nature of interactions between the solvent and solute were discussed. The obtained solubility data can be used for development of various technological processes involving thiourea, particularly for the synthesis of isopropyl mercaptan.

作者简介

Xingli Jiao

School of Chemical and Energy Engineering

Email: lihua@zzu.edu.cn
中国, Zhengzhou, 450001

Xiaoshuang Chen

Department of Mechanical Engineering

Email: lihua@zzu.edu.cn
美国, Minneapolis, MN, 55455

Hua Li

School of Chemical and Energy Engineering

编辑信件的主要联系方式.
Email: lihua@zzu.edu.cn
中国, Zhengzhou, 450001

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