Thermodynamics of thiourea dissolution in methanol–water mixtures
- 作者: Jiao X.1, Chen X.2, Li H.1
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隶属关系:
- School of Chemical and Energy Engineering
- Department of Mechanical Engineering
- 期: 卷 90, 编号 2 (2016)
- 页面: 356-359
- 栏目: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0244/article/view/167739
- DOI: https://doi.org/10.1134/S0036024416020357
- ID: 167739
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详细
The solubilities of thiourea in methanol-water mixtures with mass fraction of methanol of 0.54, 0.65, 0.76, 0.88, and 1.00 were determined. The experimental data were approximated with the modified Apelblat equation. The dissolution enthalpy and entropy were calculated from the experimental data and the nature of interactions between the solvent and solute were discussed. The obtained solubility data can be used for development of various technological processes involving thiourea, particularly for the synthesis of isopropyl mercaptan.
作者简介
Xingli Jiao
School of Chemical and Energy Engineering
Email: lihua@zzu.edu.cn
中国, Zhengzhou, 450001
Xiaoshuang Chen
Department of Mechanical Engineering
Email: lihua@zzu.edu.cn
美国, Minneapolis, MN, 55455
Hua Li
School of Chemical and Energy Engineering
编辑信件的主要联系方式.
Email: lihua@zzu.edu.cn
中国, Zhengzhou, 450001
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