Standard thermodynamic functions of Co2+ complexation with glycine and L-histidine in aqueous solution
- Authors: Gorboletova G.G.1, Metlin A.A.1
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Affiliations:
- Ivanovo State University of Chemistry and Technology
- Issue: Vol 90, No 2 (2016)
- Pages: 334-338
- Section: Physical Chemistry of Solutions
- URL: https://journals.rcsi.science/0036-0244/article/view/167712
- DOI: https://doi.org/10.1134/S0036024416010118
- ID: 167712
Cite item
Abstract
The enthalpies of the reactions between solutions of Co(NO3)2 and solutions of glycine (Gly) and L-histidine (His) are determined via direct calorimetry at different pH values and metal: ligand ratios using KNO3 as a background electrolyte (T = 298.15 K, I = 0.2–1.0). The enthalpy changes upon the formation of cobalt glycinate complexes and Co2+ mixed-ligand complex, viz., glycine–L-histidine, were calculated. The standard thermodynamic parameters (ΔrH°, ΔrG°, ΔrS°) of complexation are determined. The CoGlyHis complex is shown to be stable toward decomposition into homogeneous complexes.
About the authors
G. G. Gorboletova
Ivanovo State University of Chemistry and Technology
Author for correspondence.
Email: gorboletova@mail.ru
Russian Federation, Ivanovo, 153000
A. A. Metlin
Ivanovo State University of Chemistry and Technology
Email: gorboletova@mail.ru
Russian Federation, Ivanovo, 153000