Synthesis of β-Bromo-Substituted Cu(II) Tetraphenylporphyrinates
- 作者: Chizhova N.V.1, Shinkarenko A.V.2, Zav’yalov A.V.2, Mamardashvili N.Z.1
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隶属关系:
- Krestov Institute of Solution Chemistry
- Ivanovo State University of Chemistry and Technology
- 期: 卷 63, 编号 6 (2018)
- 页面: 732-735
- 栏目: Synthesis and Properties of Inorganic Compounds
- URL: https://journals.rcsi.science/0036-0236/article/view/168728
- DOI: https://doi.org/10.1134/S0036023618060062
- ID: 168728
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详细
Bromination reactions of Cu(II) 5,10,15,20-tetraphenylporphyrinate with N-bromosuccinimide in chloroform and chloroform–dimethylformamide mixture and complexation of 2-bromo-5,10,15,20-tetraphenylporphyrin and 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin with copper(II) acetate in dimethylformamide have been studied. Mono-, tetra-, and octabromo-substituted Cu(II) porphyrinates have been synthesized. Obtained compounds have been identified by electronic absorption spectroscopy, IR spectroscopy, mass spectrometry, and elemental analysis.
作者简介
N. Chizhova
Krestov Institute of Solution Chemistry
编辑信件的主要联系方式.
Email: nvc@isc-ras.ru
俄罗斯联邦, Ivanovo, 153040
A. Shinkarenko
Ivanovo State University of Chemistry and Technology
Email: nvc@isc-ras.ru
俄罗斯联邦, Ivanovo, 153000
A. Zav’yalov
Ivanovo State University of Chemistry and Technology
Email: nvc@isc-ras.ru
俄罗斯联邦, Ivanovo, 153000
N. Mamardashvili
Krestov Institute of Solution Chemistry
Email: nvc@isc-ras.ru
俄罗斯联邦, Ivanovo, 153040
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