A new method for the synthesis of carboxonium derivatives of the closo-decaborate anion [2,6-B10H8(O2CR)]–, where R = CH3, C2H5
- Авторы: Klyukin I.N.1, Zhdanov A.P.1, Bykov A.Y.1, Razgonyaeva G.A.1, Grigor’ev M.S.2, Zhizhin K.Y.1, Kuznetsov N.T.1
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Учреждения:
- Kurnakov Institute of General and Inorganic Chemistry
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Выпуск: Том 62, № 11 (2017)
- Страницы: 1479-1482
- Раздел: Physical Methods of Investigation
- URL: https://journals.rcsi.science/0036-0236/article/view/168151
- DOI: https://doi.org/10.1134/S0036023617110109
- ID: 168151
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Аннотация
A single-stage scheme for the synthesis of carboxonium derivatives of the closo-decaborate anion by the reaction between the [B10H11]– anion and carboxylic acids was proposed. Target compounds were separated and characterized by IR and 1H, 11B, 13C NMR spectroscopy. In addition to the target compounds, closo-decaborate cluster opening products ere formed, and in the reaction between the closo-decaborate anion and acetic acid, a polymeric product was observed. The polymeric product (Ph4P)n[2,6,3,7-B10H6O2CCH3]n was characterized by X-ray diffraction.
Об авторах
I. Klyukin
Kurnakov Institute of General and Inorganic Chemistry
Автор, ответственный за переписку.
Email: klukinil@gmail.com
Россия, Moscow, 119991
A. Zhdanov
Kurnakov Institute of General and Inorganic Chemistry
Email: klukinil@gmail.com
Россия, Moscow, 119991
A. Bykov
Kurnakov Institute of General and Inorganic Chemistry
Email: klukinil@gmail.com
Россия, Moscow, 119991
G. Razgonyaeva
Kurnakov Institute of General and Inorganic Chemistry
Email: klukinil@gmail.com
Россия, Moscow, 119991
M. Grigor’ev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: klukinil@gmail.com
Россия, Moscow, 117342
K. Zhizhin
Kurnakov Institute of General and Inorganic Chemistry
Email: klukinil@gmail.com
Россия, Moscow, 119991
N. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry
Email: klukinil@gmail.com
Россия, Moscow, 119991
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