Formation of solid solutions in the CdSe–PbSe system under the action of high pressures and temperatures

A. Yu. Chufarov; N. V. Melnikova; N. V. Zarubina; A. N. Ermakov; E. G. Vovkotrub; L. N. Maskaeva; V. F. Markov; Yu. G. Zainulin

doi:10.1134/S0036023616080052

Formation of solid solutions in the CdSe–PbSe system under the action of high pressures and temperatures

作者: Chufarov A.Y.¹, Melnikova N.V.², Zarubina N.V.², Ermakov A.N.¹, Vovkotrub E.G.³, Maskaeva L.N.², Markov V.F.², Zainulin Y.G.¹
隶属关系:
1. Institute of Solid-State Chemistry, Ural Branch
2. Yeltsin Ural Federal University
3. Institute of High-Temperature Electrochemistry, Ural Branch
期: 卷 61, 编号 8 (2016)
页面: 1013-1018
栏目: Physical Methods of Investigation
URL: https://journals.rcsi.science/0036-0236/article/view/166694
DOI: https://doi.org/10.1134/S0036023616080052
ID: 166694

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A method was proposed for producing solid solutions in the CdSe–PbSe systems, which is based on heat and high pressure treatment. X-ray powder diffraction analysis showed the formation of substitutional solid solutions Cd_xPb_1–xSe with the NaCl structure, which contained 20, 40, 60, and 80 mol % cadmium selenide. The solid solutions were characterized by scanning electron microscopy, impedance spectroscopy, gas pycnometry, and Raman spectroscopy.